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BIEŃKO, A. KOPEL, P. KIZEK, R. KRUSZYŃSKI, R. BIEŃKO, D. TIFIŠ, J. BOČA, R.
Original Title
Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes
Type
journal article in Web of Science
Language
English
Original Abstract
Magnetism of high-nuclearity complexes is currently an active field of research since it was discovered that a M12 complex exhibits single-molecule magnet (SMM) behavior [1]. However, the synthesis f such species is challenging. The synthetic route is to carefully select the bridging ligands and control the hydrolysis or alcoholysis of metal ions in the presence of auxiliary ligands. The compounds can be bridged by single atoms as well as by polyatomic bridges.The magnetic susceptibilities of all antiferromagnetic complexes were fitted by using approximate models.
Keywords
Nickel, Cobalt, Bridging ligand, Multinuclear complexes, Magnetic properties
Authors
BIEŃKO, A.; KOPEL, P.; KIZEK, R.; KRUSZYŃSKI, R.; BIEŃKO, D.; TIFIŠ, J.; BOČA, R.
RIV year
2014
Released
24. 5. 2014
ISBN
0020-1693
Periodical
INORGANICA CHIMICA ACTA
Year of study
416
Number
1
State
Swiss Confederation
Pages from
147
Pages to
156
Pages count
10
BibTex
@article{BUT112332, author="Alina {Bieńko} and Pavel {Kopel} and René {Kizek} and Rafał {Kruszyński} and Dariusz {Bieńko} and Ján {Tifiš} and Roman {Boča}", title="Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes", journal="INORGANICA CHIMICA ACTA", year="2014", volume="416", number="1", pages="147--156", doi="10.1016/j.ica.2014.03.009", issn="0020-1693" }