Publication detail

Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes

BIEŃKO, A. KOPEL, P. KIZEK, R. KRUSZYŃSKI, R. BIEŃKO, D. TIFIŠ, J. BOČA, R.

Original Title

Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes

Type

journal article in Web of Science

Language

English

Original Abstract

Magnetism of high-nuclearity complexes is currently an active field of research since it was discovered that a M12 complex exhibits single-molecule magnet (SMM) behavior [1]. However, the synthesis f such species is challenging. The synthetic route is to carefully select the bridging ligands and control the hydrolysis or alcoholysis of metal ions in the presence of auxiliary ligands. The compounds can be bridged by single atoms as well as by polyatomic bridges.The magnetic susceptibilities of all antiferromagnetic complexes were fitted by using approximate models.

Keywords

Nickel, Cobalt, Bridging ligand, Multinuclear complexes, Magnetic properties

Authors

BIEŃKO, A.; KOPEL, P.; KIZEK, R.; KRUSZYŃSKI, R.; BIEŃKO, D.; TIFIŠ, J.; BOČA, R.

RIV year

2014

Released

24. 5. 2014

ISBN

0020-1693

Periodical

INORGANICA CHIMICA ACTA

Year of study

416

Number

1

State

Swiss Confederation

Pages from

147

Pages to

156

Pages count

10

BibTex

@article{BUT112332,
  author="Alina {Bieńko} and Pavel {Kopel} and René {Kizek} and Rafał {Kruszyński} and Dariusz {Bieńko} and Ján {Tifiš} and Roman {Boča}",
  title="Synthesis, crystal structure and magnetic properties of trithiocyanurate or thiodiacetate polynuclear Ni(II) and Co(II) complexes",
  journal="INORGANICA CHIMICA ACTA",
  year="2014",
  volume="416",
  number="1",
  pages="147--156",
  doi="10.1016/j.ica.2014.03.009",
  issn="0020-1693"
}