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POSPÍŠILOVÁ, Ľ. KOMÍNKOVÁ, M. ZÍTKA, O. KÍZEK, R. BARANČÍKOVÁ, G. LITAVEC, T. LOŠÁK, T. HLUŠEK, J. MARTENSSON, A. LIPTAJ, T.
Original Title
Fate of humic acids isolated from natural humic substance
Type
journal article in Web of Science
Language
English
Original Abstract
Composition of humic acids (HA) is a function of plant-derived inputs, degradation processes regulated by microorganisms, organo-mineral interactions and age. Characterization of different origin humic substances is important for evaluation of their contribution to stabile and labile carbon pool in the environment. The relative abundance of chemical components in HA isolated from soils, compost, commercial lignohumates, alginite, acadiane and lignite was studied with aim to quantify content of important biomarkers such as amino acid, lipids and polyphenols. HA were considered as a heterogeneous complex and high concentration of peptides, polyphenols and lipids was determined in acadian-HA to compare with soil-HA. Compost-HA contained much more amino acids to compare with soil-HA samples. Alginite-HA and lignite-HA were similar in biomarkers content to soil-HA. Fourier transform infrared spectroscopy confirmed that chemical composition and functional groups content differs with the origin, humification degree and the age of studied samples. Soil-HA are typically composed of a variety of -OH, COOH-, C-O, C-H-2, (aliphatic and aromatic) groups, quinines, lignin fragments, polysaccharide, monosaccharide and proteins fragments, which are linked together by -O-, -NH-, -H=, >C=O, metal ions and -S- groups. C-13 NMR spectroscopy showed that aromatic carbon content was the highest in lignite-HA and soil-HA.
Keywords
biomarkers; FTIR and C-13 NMR spectroscopy; natural humic substances
Authors
POSPÍŠILOVÁ, Ľ.; KOMÍNKOVÁ, M.; ZÍTKA, O.; KÍZEK, R.; BARANČÍKOVÁ, G.; LITAVEC, T.; LOŠÁK, T.; HLUŠEK, J.; MARTENSSON, A.; LIPTAJ, T.
RIV year
2015
Released
18. 8. 2015
ISBN
0906-4710
Periodical
ACTA AGRICULTURAE SCANDINAVICA SECTION B-SOIL AND PLANT SCIENCE
Year of study
65
Number
6
State
Kingdom of Norway
Pages from
517
Pages to
528
Pages count
11
BibTex
@article{BUT123341, author="Ľubica {Pospíšilová} and Markéta {Komínková} and Ondřej {Zítka} and René {Kízek} and Gabriela {Barančíková} and Tadeáš {Litavec} and Tomáš {Lošák} and Jaroslav {Hlušek} and Anna {Martensson} and Tibor {Liptaj}", title="Fate of humic acids isolated from natural humic substance", journal="ACTA AGRICULTURAE SCANDINAVICA SECTION B-SOIL AND PLANT SCIENCE", year="2015", volume="65", number="6", pages="517--528", doi="10.1080/09064710.2015.1030442", issn="0906-4710" }