Publication detail

Thiophene-free diphenyl-amino-stilbene-diketo-pyrrolo-pyrrole derivatives as donors for organic bulk heterojunction solar cells

Jana Honová, Stanislav Luňák, Martin Vala, Stanislav Střítesk ́y, Ladislav Fekete, Martin Weiter, Alexander Kovalenko

Original Title

Thiophene-free diphenyl-amino-stilbene-diketo-pyrrolo-pyrrole derivatives as donors for organic bulk heterojunction solar cells

Type

journal article in Web of Science

Language

English

Original Abstract

An extended study on a group of four soluble diphenyl-amino-stilbene based diphenyl-diketopyrrolo-pyrrole molecules has been carried out. Using the materials in thin-film transistors it was shown that the above-mentioned compounds can be successfully used as donors in organic photovoltaic devices. Influence of the molecular symmetry and solubilizing chain on the morphology and solar cell performance are described. It was shown that a shorter and non-branched ethyl acetate chain leads to higher charge carrier mobility, short circuit current, and better fill factor. After the basic optimization, a power conversion efficiency of about 1.5 % was reached. This, to the best of our knowledge, is the highest reported efficiency of thiophene-free small-molecule diketo-pyrrolopyrroles.

Keywords

organic solar cell, thiophene-free, diphenyl-amino-stilbene, hole mobility, molecular structure

Authors

Jana Honová, Stanislav Luňák, Martin Vala, Stanislav Střítesk ́y, Ladislav Fekete, Martin Weiter, Alexander Kovalenko

Released

26. 5. 2016

Publisher

DE GRUYTER

Location

Germany, Berlin

ISBN

1336-9075

Periodical

Chemical Papers

Year of study

1

Number

1

State

Slovak Republic

Pages from

1

Pages to

9

Pages count

9

URL

https://www.degruyter.com/dg/journalprintahead.articlelist.resultlinks.fullcontentlink:pdfeventlink/$002fj$002fchempap.ahead-of-print$002fchempap-2016-0068$002fchempap-2016-0068.pdf/chempap-2016-0068.pdf?t:ac=j$002fchempap

BibTex

@article{BUT126481,
  author="Alexander {Kovalenko} and Jana {Vrchotová} and Stanislav {Luňák} and Martin {Vala} and Stanislav {Stříteský} and Martin {Weiter}",
  title="Thiophene-free diphenyl-amino-stilbene-diketo-pyrrolo-pyrrole derivatives as donors for organic bulk heterojunction solar cells",
  journal="Chemical Papers",
  year="2016",
  volume="1",
  number="1",
  pages="1--9",
  doi="10.1515/chempap-2016-0068",
  issn="1336-9075",
  url="https://www.degruyter.com/dg/journalprintahead.articlelist.resultlinks.fullcontentlink:pdfeventlink/$002fj$002fchempap.ahead-of-print$002fchempap-2016-0068$002fchempap-2016-0068.pdf/chempap-2016-0068.pdf?t:ac=j$002fchempap"
}