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MOTOLA, M. SOPHA, H. KRBAL, M. HROMÁDKO, L. OLMROVÁ ZMRHALOVÁ, Z. PLESCH, G. MACÁK, J.
Original Title
Comparison of photoelectrochemical performance of anodic single- and double-walled TiO2 nanotube layers
Type
journal article in Web of Science
Language
English
Original Abstract
In this work, the photoelectrochemical response of single-walled (SW) and double-walled (DW) TiO2 nanotube (TNT) layers is presented. TNT layers were grown on Ti substrates by anodization in two different ethylene glycol-based electrolytes to obtain ~5 and ~15 μm thick TNT layers. The inner shell of the TNT was quantitatively removed via a mild pre-annealing followed by a selective chemical etching treatment in piranha solution. All TNT layers were investigated for their photoelectrochemical response in the ultraviolet and near visible spectral range. Significantly enhanced photocurrent densities were revealed for the SW-TNT layers. This is ascribed to improved charge carrier separation along the tube walls due to the lack of the C- and F-rich inner shell removed by etching.
Keywords
Titanium dioxide Nanotubes Single-walled Double-walled Photoelectrochemistry
Authors
MOTOLA, M.; SOPHA, H.; KRBAL, M.; HROMÁDKO, L.; OLMROVÁ ZMRHALOVÁ, Z.; PLESCH, G.; MACÁK, J.
Released
1. 12. 2018
ISBN
1388-2481
Periodical
ELECTROCHEMISTRY COMMUNICATIONS
Year of study
97
Number
1
State
United States of America
Pages from
Pages to
5
Pages count
BibTex
@article{BUT150269, author="Martin {Motola} and Hanna Ingrid {Sopha} and Miloš {Krbal} and Luděk {Hromádko} and Zuzana {Olmrová Zmrhalová} and Gustav {Plesch} and Jan {Macák}", title="Comparison of photoelectrochemical performance of anodic single- and double-walled TiO2 nanotube layers", journal="ELECTROCHEMISTRY COMMUNICATIONS", year="2018", volume="97", number="1", pages="1--5", doi="10.1016/j.elecom.2018.09.015", issn="1388-2481" }