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Marcella Dell'Aglio, Zita Salajkova, Antonia Mallardi, Raffaele Mezzenga, Leonie Van't Hag, Nicola Cioffi, Gerardo Palazzo, Alessandro De Giacomo
Original Title
Application of gold nanoparticles embedded in the amyloids fibrils as enhancer in the Laser Induced Breakdown Spectroscopy for the metal quantification in microdroplets
Type
journal article in Web of Science
Language
English
Original Abstract
In this work Nanoparticle Enhanced Laser Induced Breakdown Spectroscopy (NELIBS) has been employed for quantitative metal detection using amyloid fibrils coated with gold nanoparticles as enhancers. Amyloid fibrils represent, from one hand, an extremely interesting system for novel technologies, spacing from water purification to medical applications, and on the other hand, an ideal system for investigating the performance of laser-matter interaction in biological systems. The results obtained in this work show the potentiality of NELIBS for the quantification at sub-ppm (mg/Kg) level of metallic elements (Cr, Pb, Tl and Cd) even in the protein and/or biological environment, employing amyloid fibrils with gold nanoparticles. Moreover, the singleshot measurements reveal the promising use of this technique in applications where high sensitivity and/or limitation in the sample amount are demanded.
Keywords
Nanoparticle enhanced LIBS, amyloids fibrils, gold nanoparticles, microdroplets,trace elements
Authors
Released
1. 4. 2019
Publisher
Spectrochimica Acta Part B: Atomic Spectroscopy
ISBN
0584-8547
Periodical
Spectrochimica Acta Part B
Number
8
State
United Kingdom of Great Britain and Northern Ireland
Pages from
115
Pages to
122
Pages count
7
URL
https://doi.org/10.1016/j.sab.2019.04.002
BibTex
@article{BUT156475, author="Zita {Salajková}", title="Application of gold nanoparticles embedded in the amyloids fibrils as enhancer in the Laser Induced Breakdown Spectroscopy for the metal quantification in microdroplets", journal="Spectrochimica Acta Part B", year="2019", number="8", pages="115--122", doi="10.1016/j.sab.2019.04.002", issn="0584-8547", url="https://doi.org/10.1016/j.sab.2019.04.002" }