Publication detail

Determination of zero-field splitting in Co2+ halide complexes with magnetic and far-IR measurements

Liu, JJ. Meng, YS. Hlavicka, I. Orlita, M. Jiang, SD. Wang, BW. Gao, S.

Original Title

Determination of zero-field splitting in Co2+ halide complexes with magnetic and far-IR measurements

Type

journal article in Web of Science

Language

English

Original Abstract

Three penta-coordinate Co2+ complexes with halide substitutes were synthesized. Their zero-field splitting (ZFS) parameters were determined by fitting dc magnetic data and far-infrared magneto- transmission spectra. The results gave an unusual case that complexes with heavier halide atoms bear smaller ZFS parameters.

Keywords

SINGLE-MOLECULE MAGNETS; COBALT(II) COMPLEX; CO(II) COMPLEXES; METAL-COMPLEXES; LIGANDS AFFECT; ANISOTROPY; RELAXATION; EPR; SERIES; ION

Authors

Liu, JJ.; Meng, YS.; Hlavicka, I. ; Orlita, M.; Jiang, SD.; Wang, BW.; Gao, S.

Released

21. 6. 2017

Publisher

ROYAL SOC CHEMISTRY

Location

CAMBRIDGE

ISBN

1477-9234

Periodical

Dalton Transactions

Year of study

46

Number

23

State

United Kingdom of Great Britain and Northern Ireland

Pages from

7408

Pages to

7411

Pages count

4

URL

https://pubs.rsc.org/en/content/articlehtml/2017/dt/c7dt01486d

BibTex

@article{BUT163365,
  author="Liu, JJ. and Meng, YS. and Hlavicka, I. and Orlita, M. and Jiang, SD. and Wang, BW. and Gao, S.",
  title="Determination of zero-field splitting in Co2+ halide complexes with magnetic and far-IR measurements",
  journal="Dalton Transactions",
  year="2017",
  volume="46",
  number="23",
  pages="7408--7411",
  doi="10.1039/c7dt01486d",
  issn="1477-9234",
  url="https://pubs.rsc.org/en/content/articlehtml/2017/dt/c7dt01486d"
}