Publication detail
Co(II)-Based single-ion magnets with 1,1 '-ferrocenediyl-bis(diphenylphosphine) metalloligands
HRUBÝ, J. DVOŘÁK, D. SQUILLANTINI, L. MANNINI, M. VAN SLAGEREN, J. HERCHEL, R. NEMEC, I. NEUGEBAUER, P.
Original Title
Co(II)-Based single-ion magnets with 1,1 '-ferrocenediyl-bis(diphenylphosphine) metalloligands
Type
journal article in Web of Science
Language
English
Original Abstract
Herein, we report on investigations of magnetic and spectroscopic properties of three heterobimetallic Fe(ii)-Co(ii) coordination compounds based on the tetracoordinate {CoP2X2} core encapsulated by dppf metalloligand, where X = Cl (1), Br (2), I (3), dppf = 1,1 '-ferrocenediyl -bis(diphenylphosphine). The analysis of static magnetic data has revealed the presence of axial magnetic anisotropy in compounds (1) and (2) and this was further confirmed by high-frequency electron spin resonance (HF-ESR) spectroscopy. Dynamic magnetic data confirmed that (1) and (2) behave as field-induced Single-Ion Magnets (SIMs). Together with bulk studies, we have also tested the possibility of depositing (2) as thick films on Au(111), glass, and polymeric acetate by drop-casting as well as thermal sublimation, a key aspect for the development of future devices embedding these magnetic objects.
Keywords
STATE PERTURBATION-THEORY; INDUCED SLOW RELAXATION; MONONUCLEAR COBALT(II) COMPLEX; TRANSITION-METAL-COMPLEXES; ZERO-FIELD; LIGAND-FIELD; HETEROPOLYMETALLIC COMPLEXES; MAGNETIZATION RELAXATION; MOLECULE MAGNET; HARTREE-FOCK
Authors
HRUBÝ, J.; DVOŘÁK, D.; SQUILLANTINI, L.; MANNINI, M.; VAN SLAGEREN, J.; HERCHEL, R.; NEMEC, I.; NEUGEBAUER, P.
Released
7. 9. 2020
Publisher
Royal Society of Chemistry
Location
CAMBRIDGE
ISBN
1477-9234
Periodical
Dalton Transactions
Year of study
49
Number
33
State
United Kingdom of Great Britain and Northern Ireland
Pages from
11697
Pages to
11707
Pages count
11
URL
Full text in the Digital Library
BibTex
@article{BUT165497,
author="Jakub {Hrubý} and Dalibor {Dvořák} and Lorenzo {Squillantini} and Mateo {Mannini} and Joris {van Slageren} and Radovan {Herchel} and Ivan {Nemec} and Petr {Neugebauer}",
title="Co(II)-Based single-ion magnets with 1,1 '-ferrocenediyl-bis(diphenylphosphine) metalloligands",
journal="Dalton Transactions",
year="2020",
volume="49",
number="33",
pages="11697--11707",
doi="10.1039/d0dt01512a",
issn="1477-9234",
url="https://pubs.rsc.org/en/content/articlehtml/2020/dt/d0dt01512a"
}