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KLEMENT, R. DRDLÍKOVÁ, K. DRDLÍK, D. MACA, K. GALUSEK, D.
Original Title
Analysis of optical properties of Al2O3:Cr3+ polycrystalline transparent red light emmiting ceramics
Type
article in a collection out of WoS and Scopus
Language
English
Original Abstract
Transparent Cr3+-doped alumina ceramics was prepared by slip casting, followed by pre-sintering in ambient atmosphere and hot isostatic pressing. The effect of dopant concentration on optical (transmission and photoluminescence-PL) properties was studied. Two approaches were used for treatment and comparison of the transmission data, one based on simple total background correction and other based on Rayleigh-Gans-Debye approximation that includes birefringent grain scattering effect. The PL spectra of studied samples exhibit intensive deep red narrow emissions under violet/green light excitation, R-lines (2Eg4A2g transition), observed at 692.5 and 693.8 nm, that are very close to ruby single crystal. The highest emission was achieved at the Cr3+ concentration of 0.4 at. %. The luminescence decay curves exhibit single-exponential behaviour with decay times of 3.6 ms.
Keywords
Cr3+-doped Al2O3; transparent polycrystalline ceramics; optical properties; luminescence
Authors
KLEMENT, R.; DRDLÍKOVÁ, K.; DRDLÍK, D.; MACA, K.; GALUSEK, D.
Released
20. 11. 2019
Publisher
Institute of Inorganic Chemistry, SAS
Location
Bratislava
ISBN
978-80-971648-8-1
Book
Processing and properties of advanced ceramics and glasses
Edition number
1
Pages from
101
Pages to
111
Pages count
11
BibTex
@inproceedings{BUT166181, author="Róbert {Klement} and Katarina {Drdlíková} and Daniel {Drdlík} and Karel {Maca} and Dušan {Galusek}", title="Analysis of optical properties of Al2O3:Cr3+ polycrystalline transparent red light emmiting ceramics", booktitle="Processing and properties of advanced ceramics and glasses", year="2019", number="1", pages="101--111", publisher="Institute of Inorganic Chemistry, SAS", address="Bratislava", isbn="978-80-971648-8-1" }