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SOPHA, H. GHIGO, C. NG, S. ALIJANI, M. HROMÁDKO, L. MICHALIČKA, J. DJENIZIAN, T. MACÁK, J.
Original Title
TiO2 nanotube layers decorated by titania nanoparticles as anodes for Li-ion microbatteries
Type
journal article in Web of Science
Language
English
Original Abstract
In this work, the utilization of TiO2 nanotube (TNT) layers decorated with TiO2 nanoparticles (NPs) as anodes in Li-ion microbatteries is reported for the first time. Such TiO2 NPs decorated TNT layers possess an increased amount of active material and a higher surface area compared with their non-decorated (blank) counterparts. TNT layers decorated with several different amounts of TiO2 NPs were tested by galvanostatic cycling tests. The capacities of the TiO2 NPs decorated TNT layer anodes increase with the amount of NPs decoration due to the enhancement of the capacitive effect. Indeed, an areal capacity of -126 pAh cm(-2) (vs 88 pAh cm(-2) for the non decorated TNT layer) at the 200th cycle has been obtained after optimizing the NPs loading. On the other hand, a too high NPs loading of the TNT layers leads to a reduced areal capacity due to clogging of the nanotube exteriors and a significant decrease in inner diameter of the nanotubes.
Keywords
TiO2 nanotube layers; TiO2 nanoparticles; Decoration; Li-ion microbatteries
Authors
SOPHA, H.; GHIGO, C.; NG, S.; ALIJANI, M.; HROMÁDKO, L.; MICHALIČKA, J.; DJENIZIAN, T.; MACÁK, J.
Released
15. 1. 2022
Publisher
Elsevier
Location
LAUSANNE
ISBN
1879-3312
Periodical
MATERIALS CHEMISTRY AND PHYSICS
Year of study
276
Number
1
State
Swiss Confederation
Pages from
Pages to
7
Pages count
URL
https://www.sciencedirect.com/science/article/pii/S0254058421011202
Full text in the Digital Library
http://hdl.handle.net/11012/203283
BibTex
@article{BUT173234, author="Hanna Ingrid {Sopha} and Clement {Ghigo} and Siow Woon {Ng} and Mahnaz {Alijani} and Luděk {Hromádko} and Jan {Michalička} and Thierry {Djenizian} and Jan {Macák}", title="TiO2 nanotube layers decorated by titania nanoparticles as anodes for Li-ion microbatteries", journal="MATERIALS CHEMISTRY AND PHYSICS", year="2022", volume="276", number="1", pages="1--7", doi="10.1016/j.matchemphys.2021.125337", issn="1879-3312", url="https://www.sciencedirect.com/science/article/pii/S0254058421011202" }