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VODOVÁ, M. NEJDL, L. PAVELICOVÁ, K. ZEMÁNKOVÁ, K. RÝPAR, T. ŠTĚRBOVÁ, D. BEZDĚKOVÁ, J. NUCHTAVORN, N. MACKA, M. ADAM, V. VACULOVIČOVÁ, M.
Original Title
Detection of pesticides in food products using paper-based devices by UV-induced fluorescence spectroscopy combined with molecularly imprinted polymers
Type
journal article in Web of Science
Language
English
Original Abstract
In this proof-of-concept study, we explore the detection of pesticides in food using a combined power of sensitive UV-induced fingerprint spectroscopy with selective capture by molecularly imprinted polymers (MIPs) and portable cost-effective paper-based analytical devices (PADs). The specific pesticides used herein as model compounds (both pure substances and their application products for spraying), were: strobilurins (i.e. trifloxystrobin), urea pesticides (rimsulfuron), pyrethroids (cypermethrine) and aryloxyphenoxyproponic acid herbicides (Haloxyfop-methyl). Commercially available spraying formulations containing the selected pesticides were positively identified by MIP-PADs swabs of sprayed apple and tomato. The key properties of MIP layer – imprinting factor (IF) and selectivity factor (α) were characterized using trifloxystrobin (IF-3.5, α-4.4) was demonstrated as a potential option for in-field application. The presented method may provide effective help with in-field testing of food and reveal problems such as false product labelling.
Keywords
Photochemistry; fingerprint; molecularly imprinted polymers; pesticides; UV-induced fluorescence fingerprinting
Authors
VODOVÁ, M.; NEJDL, L.; PAVELICOVÁ, K.; ZEMÁNKOVÁ, K.; RÝPAR, T.; ŠTĚRBOVÁ, D.; BEZDĚKOVÁ, J.; NUCHTAVORN, N.; MACKA, M.; ADAM, V.; VACULOVIČOVÁ, M.
Released
30. 6. 2022
ISBN
0308-8146
Periodical
FOOD CHEMISTRY
Year of study
380
Number
132141
State
United Kingdom of Great Britain and Northern Ireland
Pages from
1
Pages to
9
Pages count
URL
https://doi.org/10.1016/j.foodchem.2022.132141
BibTex
@article{BUT176899, author="Milada {Vodová} and Lukáš {Nejdl} and Kristýna {Pavelicová} and Kristýna {Zemánková} and Tomáš {Rýpar} and Dagmar {Štěrbová} and Jaroslava {Bezděková} and Nantana {Nuchtavorn} and Miroslav {Macka} and Vojtěch {Adam} and Markéta {Vaculovičová}", title="Detection of pesticides in food products using paper-based devices by UV-induced fluorescence spectroscopy combined with molecularly imprinted polymers", journal="FOOD CHEMISTRY", year="2022", volume="380", number="132141", pages="1--9", doi="10.1016/j.foodchem.2022.132141", issn="0308-8146", url="https://doi.org/10.1016/j.foodchem.2022.132141" }