Publication detail

Effect of extrusion process and various elongation ratios on the structural and dielectric properties of PVDF-based copolymer containing micro and nano-sized crystallites

MRLÍK, M. CVEK, M. OSIČKA, J. MASLOWSKI, M. TOFEL, P.

Original Title

Effect of extrusion process and various elongation ratios on the structural and dielectric properties of PVDF-based copolymer containing micro and nano-sized crystallites

Type

conference paper

Language

English

Original Abstract

In this contribution, the effect of the extrusion process of the poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-co-HFP) with the subsequent elongation/poling on its structural and dielectric properties is presented. The extrusion can be understood as continuous processing of polymer melts in the large scale (in comparison to solvent casting), when the thickness of the final product can be varied depending on the final operation conditions. Herein, the PVDF-co-HFP sheets of 5 cm in width were extruded using a single screw extruder. The fabricated sheets were cooled down and then, they were cut to the stripes and subsequently stretched to various elongations (100, 200 and 500 %) using a universal tensile testing machine. Such samples were investigated using FTIR in order to determine the effect of the elongation process on the transformation of the alpha-phase to the beta-crystalline phase. The extend of the electro-active beta-phase was quantified and its impact on the dielectric properties was investigated. The results clearly demonstrated that the elongation has a crucial effect on the final dielectric properties of the PVDF-co-HFP.

Keywords

Poly(vinylidene fluoride); poly(vinylidene fluoride-co-hexafluoropropylene); extrusion; dielectric properties; electromechanical coupling

Authors

MRLÍK, M.; CVEK, M.; OSIČKA, J.; MASLOWSKI, M.; TOFEL, P.

Released

11. 7. 2021

Publisher

TANGER Ltd.

Location

SLEZSKA

ISBN

978-80-87294-98-7

Book

12th International Conference on Nanomaterials - Research & Application

Pages from

127

Pages to

132

Pages count

6

URL

https://www.confer.cz/nanocon/2020/3694-effect-of-extrusion-process-and-various-elongation-ratios-on-the-structural-and-dielectric-properties-of-pvdf-based-copolymer-containing-micro-and-nano-sized-crystalites

Full text in the Digital Library

http://hdl.handle.net/11012/204069

BibTex

@inproceedings{BUT177336,
  author="Miroslav {Mrlík} and Martin {Cvek} and Josef {Osička} and Marcin {Maslowski} and Pavel {Tofel}",
  title="Effect of extrusion process and various elongation ratios on the structural and dielectric properties of PVDF-based copolymer containing micro and nano-sized crystallites",
  booktitle="12th International Conference on Nanomaterials - Research & Application",
  year="2021",
  pages="127--132",
  publisher="TANGER Ltd.",
  address="SLEZSKA",
  doi="10.37904/nanocon.2020.3694",
  isbn="978-80-87294-98-7",
  url="https://www.confer.cz/nanocon/2020/3694-effect-of-extrusion-process-and-various-elongation-ratios-on-the-structural-and-dielectric-properties-of-pvdf-based-copolymer-containing-micro-and-nano-sized-crystalites"
}