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JURÁKOVÁ, J. ŠALITROŠ, I.
Original Title
Co(II) single-ion magnets: synthesis, structure, and magnetic properties
Type
journal article in Web of Science
Language
English
Original Abstract
Magnetoactive coordination compounds exhibiting bi- or multistability between two or more magnetic stable states present an attractive example of molecular switches. Currently, the research is focused on molecular nanomagnets, especially single molecule magnets (SMMs), which are molecules, where the slow relaxation of the magnetization based on the purely molecular origin is observed. Contrary to ferromagnets, the magnetic bistability of SMMs does not require intermolecular interactions, which makes them particularly interesting in terms of application potential, especially in the high-density storage of data. This paper aims to introduce the readers into a basic understanding of SMM behaviour, and furthermore, it provides an overview of the attractive Co(II) SMMs with emphasis on the relation between structural features, magnetic anisotropy, and slow relaxation of magnetization in tetra-, penta-, and hexacoordinate complexes. [GRAPHICS] .
Keywords
Coordination chemistry; Molecular magnets; Magnetic properties; Coordination geometry
Authors
JURÁKOVÁ, J.; ŠALITROŠ, I.
Released
1. 11. 2022
Publisher
SPRINGER WIEN
Location
WIEN
ISBN
1434-4475
Periodical
Monatshefte für Chemie
Year of study
153
Number
11
State
Republic of Austria
Pages from
1001
Pages to
1036
Pages count
36
URL
https://link.springer.com/article/10.1007/s00706-022-02920-0
BibTex
@article{BUT178461, author="Jana {Juráková} and Ivan {Šalitroš}", title="Co(II) single-ion magnets: synthesis, structure, and magnetic properties", journal="Monatshefte für Chemie", year="2022", volume="153", number="11", pages="1001--1036", doi="10.1007/s00706-022-02920-0", issn="1434-4475", url="https://link.springer.com/article/10.1007/s00706-022-02920-0" }