Publication detail

Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry

MUÑOZ MARTIN, J. PALACIOS CORELLA, M. GOMEZ PEREZ, I. ZAJÍČKOVÁ, L. PUMERA, M.

Original Title

Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry

Type

journal article in Web of Science

Language

English

Original Abstract

Succeeding graphene, 2D inorganic materials made of reactive van der Waals layers, like 2D germanane (2D-Ge) derivatives, have attracted great attention because their physicochemical characteristics can be entirely tuned by modulating the nature of the surface substituent. Although very interesting from a scientific point of view, almost all the reported works involving 2D-Ge derivatives are focused on computational studies. Herein, a first prototype of organic-inorganic 2D-Ge heterostructure has been synthesized by covalently anchoring thiol-rich carbon dots (CD-SH) onto 2D allyl germanane (2D-aGe) via a simple and green "one-pot" click chemistry approach. Remarkably, the implanted characteristics of the carbon nanomaterial provide new physicochemical features to the resulting 0D/2D heterostructure, making possible its implementation in yet unexplored optoelectronic tasks-e.g., as a fluorescence resonance energy transfer (FRET) sensing system triggered by supramolecular pi-pi interactions-that are inaccessible for the pristine 2D-aGe counterpart. Consequently, this work builds a foundation toward the robust achievement of functional organic-inorganic 2D-Ge nanoarchitectonics through covalently assembling thiol-rich carbon nanoallotropes on commercially available 2D-aGe.

Keywords

2D materials; carbon dots; fluorescence resonance energy transfer; optoelectronics; thiol-ene

Authors

MUÑOZ MARTIN, J.; PALACIOS CORELLA, M.; GOMEZ PEREZ, I.; ZAJÍČKOVÁ, L.; PUMERA, M.

Released

1. 11. 2022

Publisher

WILEY-V C H VERLAG GMBH

Location

WEINHEIM

ISBN

1521-4095

Periodical

ADVANCED MATERIALS

Year of study

34

Number

45

State

Federal Republic of Germany

Pages count

8

URL

BibTex

@article{BUT181617,
  author="Jose Maria {Muñoz Martin} and Mario {Palacios Corella} and Inmaculada Jennifer {Gomez Perez} and Lenka {Zajíčková} and Martin {Pumera}",
  title="Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry",
  journal="ADVANCED MATERIALS",
  year="2022",
  volume="34",
  number="45",
  pages="8",
  doi="10.1002/adma.202206382",
  issn="1521-4095",
  url="https://onlinelibrary.wiley.com/doi/10.1002/adma.202206382"
}