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MUÑOZ MARTIN, J. PALACIOS CORELLA, M. GOMEZ PEREZ, I. ZAJÍČKOVÁ, L. PUMERA, M.
Original Title
Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry
Type
journal article in Web of Science
Language
English
Original Abstract
Succeeding graphene, 2D inorganic materials made of reactive van der Waals layers, like 2D germanane (2D-Ge) derivatives, have attracted great attention because their physicochemical characteristics can be entirely tuned by modulating the nature of the surface substituent. Although very interesting from a scientific point of view, almost all the reported works involving 2D-Ge derivatives are focused on computational studies. Herein, a first prototype of organic-inorganic 2D-Ge heterostructure has been synthesized by covalently anchoring thiol-rich carbon dots (CD-SH) onto 2D allyl germanane (2D-aGe) via a simple and green "one-pot" click chemistry approach. Remarkably, the implanted characteristics of the carbon nanomaterial provide new physicochemical features to the resulting 0D/2D heterostructure, making possible its implementation in yet unexplored optoelectronic tasks-e.g., as a fluorescence resonance energy transfer (FRET) sensing system triggered by supramolecular pi-pi interactions-that are inaccessible for the pristine 2D-aGe counterpart. Consequently, this work builds a foundation toward the robust achievement of functional organic-inorganic 2D-Ge nanoarchitectonics through covalently assembling thiol-rich carbon nanoallotropes on commercially available 2D-aGe.
Keywords
2D materials; carbon dots; fluorescence resonance energy transfer; optoelectronics; thiol-ene
Authors
MUÑOZ MARTIN, J.; PALACIOS CORELLA, M.; GOMEZ PEREZ, I.; ZAJÍČKOVÁ, L.; PUMERA, M.
Released
1. 11. 2022
Publisher
WILEY-V C H VERLAG GMBH
Location
WEINHEIM
ISBN
1521-4095
Periodical
ADVANCED MATERIALS
Year of study
34
Number
45
State
Federal Republic of Germany
Pages count
8
URL
https://onlinelibrary.wiley.com/doi/10.1002/adma.202206382
BibTex
@article{BUT181617, author="Jose Maria {Muñoz Martin} and Mario {Palacios Corella} and Inmaculada Jennifer {Gomez Perez} and Lenka {Zajíčková} and Martin {Pumera}", title="Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry", journal="ADVANCED MATERIALS", year="2022", volume="34", number="45", pages="8", doi="10.1002/adma.202206382", issn="1521-4095", url="https://onlinelibrary.wiley.com/doi/10.1002/adma.202206382" }