Přístupnostní navigace
E-application
Search Search Close
Publication detail
HORÁK, M. ČALKOVSKÝ, V. MACH, J. KŘÁPEK, V. ŠIKOLA, T.
Original Title
Plasmonic Properties of Individual Gallium Nanoparticles
Type
journal article in Web of Science
Language
English
Original Abstract
Gallium is a plasmonic material offering ultraviolet to near-infrared tunability, facile and scalable preparation, and good stability of nanoparticles. In this work, we experimentally demonstrate the link between the shape and size of individual gallium nanoparticles and their optical properties. To this end, we utilize scanning transmission electron microscopy combined with electron energy loss spectroscopy. Lens-shaped gallium nanoparticles with a diameter between 10 and 200 nm were grown directly on a silicon nitride membrane using an effusion cell developed in house that was operated under ultra-high-vacuum conditions. We have experimentally proven that they support localized surface plasmon resonances and their dipole mode can be tuned through their size from the ultraviolet to near-infrared spectral region. The measurements are supported by numerical simulations using realistic particle shapes and sizes. Our results pave the way for future applications of gallium nanoparticles such as hyperspectral absorption of sunlight in energy harvesting or plasmon-enhanced luminescence of ultraviolet emitters.
Keywords
Electron energy loss spectroscopy; Energy; Gallium; Nanoparticles; Plasmonic nanoparticles
Authors
HORÁK, M.; ČALKOVSKÝ, V.; MACH, J.; KŘÁPEK, V.; ŠIKOLA, T.
Released
16. 2. 2023
Publisher
American Chemical Society
Location
WASHINGTON
ISBN
1948-7185
Periodical
J PHYS CHEM LETT
Year of study
14
Number
8
State
United States of America
Pages from
2012
Pages to
2019
Pages count
URL
https://pubs.acs.org/doi/10.1021/acs.jpclett.3c00094
Full text in the Digital Library
http://hdl.handle.net/11012/213730
BibTex
@article{BUT183337, author="Michal {Horák} and Vojtěch {Čalkovský} and Jindřich {Mach} and Vlastimil {Křápek} and Tomáš {Šikola}", title="Plasmonic Properties of Individual Gallium Nanoparticles", journal="J PHYS CHEM LETT", year="2023", volume="14", number="8", pages="2012--2019", doi="10.1021/acs.jpclett.3c00094", issn="1948-7185", url="https://pubs.acs.org/doi/10.1021/acs.jpclett.3c00094" }