Publication detail

Influence of HCP/BCC interface orientation on the tribological behavior of Zr/Nb multilayer during nanoscratch: A combined experimental and atomistic study

ALMOTASEM, A. DAGHBOUJ, N. SEN, H. MIRZAEI, S. CALLISTI, M. POLCAR, T.

Original Title

Influence of HCP/BCC interface orientation on the tribological behavior of Zr/Nb multilayer during nanoscratch: A combined experimental and atomistic study

Type

journal article in Web of Science

Language

English

Original Abstract

Zr/Nb6 multilayers of 6 nm periodicity, with well-composition-modulated structures, were prepared by magnetron sputtering. Their microstructure and scratch properties were investigated using HAADF-STEM, XRD, AFM, and triboindenter. The Zr/Nb interfaces have various orientations along the growth direction. The hardness (H) and reduced elastic modulus (E) are measured as 6.6 GPa, and 176.3 GPa, respectively, resulting in a high ratio of H/E, compared to other multilayer systems such as Ta/Co and Ag/Cu, which indicates superior tribological performance. The coefficient of friction (COF) was 0.27, and the elastic recovery was observed along the scratch path. Extensive large molecular dynamics simulations (MD) were conducted to investigate the impact of different Zr/Nb interface orientations on the friction/wear behavior of Zr/Nb6 multilayers. The primary cause of plastic deformation of the Nb layer was dislocations and BCC twinning, while Zr layers deform via dislocations and intrinsic stacking faults. The Zr/Nb6 exhibited better tribological properties, such as lower COF, higher scratch hardness, and improved wear resistance compared to their single-crystal counterparts. The PitschSchrader interface showed the lowest COF value, whereas Rong-Dunlop and Zhang-Killy orientations exhibited better wear resistance. The interface structure was analyzed, and its blocking strength was discussed. These findings contribute to understanding the relationship between Zr/Nb interface and wear performance and tailoring them to achieve desired properties for specific applications.

Keywords

Zr; Nb nanolayers; Interface; Nanoscratch; MD; Dislocations

Authors

ALMOTASEM, A.; DAGHBOUJ, N.; SEN, H.; MIRZAEI, S.; CALLISTI, M.; POLCAR, T.

Released

1. 5. 2023

Publisher

PERGAMON-ELSEVIER SCIENCE LTD

Location

OXFORD

ISBN

1873-2453

Periodical

ACTA MATERIALIA

Year of study

249

Number

118832

State

United States of America

Pages count

12

URL

https://www.sciencedirect.com/science/article/pii/S1359645423001635?via%3Dihub

BibTex

@article{BUT183942,
  author="Ahmed Tamer {AlMotasem} and Nabil {Daghbouj} and Huseyin Sener {Sen} and Saeed {Mirzaei} and Mauro {Callisti} and Tomáš {Polcar}",
  title="Influence of HCP/BCC interface orientation on the tribological behavior of Zr/Nb multilayer during nanoscratch: A combined experimental and atomistic study",
  journal="ACTA MATERIALIA",
  year="2023",
  volume="249",
  number="118832",
  pages="12",
  doi="10.1016/j.actamat.2023.118832",
  issn="1873-2453",
  url="https://www.sciencedirect.com/science/article/pii/S1359645423001635?via%3Dihub"
}