Publication detail

A differential scanning calorimetry (DSC) approach for assessing the quality of polyethylene terephthalate (PET) waste for physical recycling: a proof-of-concept study

ŠUDOMOVÁ, L. DOLEŽALOVÁ WEISSMANNOVÁ, STEINMENTZ Z. H. ŘEZÁČOVÁ, V. KUČERÍK, J.

Original Title

A differential scanning calorimetry (DSC) approach for assessing the quality of polyethylene terephthalate (PET) waste for physical recycling: a proof-of-concept study

Type

journal article in Web of Science

Language

English

Original Abstract

Physical recycling of plastics is among the most important approaches of circular economy. The efficiency of the recycling is influenced by many factors including the number of recycling cycles, composition of plastics, chemical modifications, additives and others. Currently, however, there are no methods enabling to distinguish the quality of plastics for recycling. In this work, we address this issue and suggest a new method based on the correlation of solely thermophysical properties of polyethylene terephthalate (PET) waste obtained using differential scanning calorimetry (DSC) during repeated heating and cooling. The combination of results of differential scanning calorimetry and advanced statistical methods enabled to separate 76 PET samples into six groups according to their origin, chemical modification, degradation and suitability for recycling. The discriminant analysis enabled to suggest a model which uses for the discrimination a combination of temperatures and enthalpies of melting and crystallization. The approach illustrates that thermophysical properties, which can be obtained using a single DSC experiment, can be used to distinguish the polymers of various origin and quality.

Keywords

Polyethylene terephthalate; PET; PET-G; DSC; Recycling; Model

Authors

ŠUDOMOVÁ, L.; DOLEŽALOVÁ WEISSMANNOVÁ, STEINMENTZ Z.; H.; ŘEZÁČOVÁ, V.; KUČERÍK, J.

Released

8. 8. 2023

Publisher

Springer Nature

Location

DORDRECHT

ISBN

1588-2926

Periodical

Journal of Thermal Analysis and Calorimetry

Year of study

148

Number

20

State

Hungary

Pages from

10843

Pages to

10855

Pages count

13

URL

https://link.springer.com/article/10.1007/s10973-023-12430-8

Full text in the Digital Library

http://hdl.handle.net/11012/245018

BibTex

@article{BUT184759,
  author="Lucie {Šudomová} and Helena {Doležalová Weissmannová} and Zacharias {Steinmetz} and Veronika {Řezáčová} and Jiří {Kučerík}",
  title="A differential scanning calorimetry (DSC) approach for assessing the quality of polyethylene terephthalate (PET) waste for physical recycling: a proof-of-concept study",
  journal="Journal of Thermal Analysis and Calorimetry",
  year="2023",
  volume="148",
  number="20",
  pages="10843--10855",
  doi="10.1007/s10973-023-12430-8",
  issn="1588-2926",
  url="https://link.springer.com/article/10.1007/s10973-023-12430-8"
}