Publication detail

Polymeric Benzothiadiazole, Benzooxadiazole, and Benzoselenadiazole Photocathodes for Photocatalytic Oxygen Reduction to Hydrogen Peroxide

GANCZARCZYK, R. RYBAKIEWICZ-SEKITA, R. GRYSZEL, M. DRÁPALA, J. ZAGÓRSKA, M. GLOWACKI, E.

Original Title

Polymeric Benzothiadiazole, Benzooxadiazole, and Benzoselenadiazole Photocathodes for Photocatalytic Oxygen Reduction to Hydrogen Peroxide

Type

journal article in Web of Science

Language

English

Original Abstract

Visible-light-driven semiconductor photoelectrodes are promising new devices for on-demand photocathodic generation of hydrogen peroxide. Herein, the fabrication of organic polymeric photocathodes employing poly(4,7-di(thiophen-2-yl)benzo[c][1,2,5]thiadiazole) (pThBTD), and comparatively seven other related derivatives is reported. The monomer dithienobenzodithiazole can be directly polymerized on an electrode via two methods: electropolymerization or iodine-vapor-assisted polymerization. Both give polymers with wide visible light absorption and suitable stability for photoelectrodes. These methods yield different active layer morphologies, with electropolymerization yielding photocathodes with better performance. Critical issues affecting oxygen reduction photocurrents are evaluated, namely thickness, wettability, and pH. Photocathodic oxygen reduction currents, as well as photovoltages, are among the highest reported for an organic photoelectrocatalyst, and pThBTD films can stably produce H2O2 with high faradaic yield over at least 8 h. This work shows that single-component organic semiconductor devices can be highly competitive versus more complex heterostructures and that such low-bandgap organic polymers can afford remarkable stability.

Keywords

benzooxadiazole; benzoselenadiazole; benzothiadiazole; electroactive polymers; hydrogen peroxide generation; photocathode

Authors

GANCZARCZYK, R.; RYBAKIEWICZ-SEKITA, R.; GRYSZEL, M.; DRÁPALA, J.; ZAGÓRSKA, M.; GLOWACKI, E.

Released

1. 7. 2023

Publisher

Wiley

Location

HOBOKEN

ISBN

2196-7350

Periodical

Advanced Materials Interfaces

Year of study

10

Number

21

State

Federal Republic of Germany

Pages count

12

URL

https://onlinelibrary.wiley.com/doi/10.1002/admi.202300270

Full text in the Digital Library

http://hdl.handle.net/11012/244983

BibTex

@article{BUT184911,
  author="Roman Mateusz {Gańczarczyk} and Renata {Rybakiewicz-Sekita} and Maciej {Gryszel} and Jakub {Drápala} and Malgorzata {Zagórska} and Eric Daniel {Glowacki}",
  title="Polymeric Benzothiadiazole, Benzooxadiazole, and Benzoselenadiazole Photocathodes for Photocatalytic Oxygen Reduction to Hydrogen Peroxide",
  journal="Advanced Materials Interfaces",
  year="2023",
  volume="10",
  number="21",
  pages="12",
  doi="10.1002/admi.202300270",
  issn="2196-7350",
  url="https://onlinelibrary.wiley.com/doi/10.1002/admi.202300270"
}