Publication detail

Nanodroplet Flight Control in Electrohydrodynamic Redox 3D Printing

MENÉTREY, M. ZEZULKA, L. FANDRÉ, P. SCHMID, F. SPOLENAK, R.

Original Title

Nanodroplet Flight Control in Electrohydrodynamic Redox 3D Printing

Type

journal article in Web of Science

Language

English

Original Abstract

Electrohydrodynamic 3D printing is an additive manufacturing technique with enormous potential in plasmonics, microelectronics, and sensing applications thanks to its broad material palette, high voxel deposition rate, and compatibility with various substrates. However, the electric field used to deposit material is concentrated at the depositing structure, resulting in the focusing of the charged droplets and geometry-dependent landing positions, which complicates the fabrication of complex 3D shapes. The low level of concordance between the design and printout seriously impedes the development of electrohydrodynamic 3D printing and rationalizes the simplicity of the designs reported so far. In this work, we break the electric field centrosymmetry to study the resulting deviation in the flight trajectory of the droplets. Comparison of experimental outcomes with predictions of an FEM model provides new insights into the droplet characteristics and unveils how the product of droplet size and charge uniquely governs its kinematics. From these insights, we develop reliable predictions of the jet trajectory and allow the computation of optimized printing paths counterbalancing the electric field distortion, thereby enabling the fabrication of geometries with unprecedented complexity.

Keywords

electrostatic deflection; autofocusing effect; charged droplet; correctedprinting path; electrohydrodynamicredox 3D printing

Authors

MENÉTREY, M.; ZEZULKA, L.; FANDRÉ, P.; SCHMID, F.; SPOLENAK, R.

Released

29. 12. 2023

Publisher

AMER CHEMICAL SOC

Location

WASHINGTON

ISBN

1944-8244

Periodical

ACS APPL MATER INTER

Year of study

16

Number

1

State

United States of America

Pages from

1283

Pages to

1292

Pages count

10

URL

BibTex

@article{BUT187335,
  author="MENÉTREY, M. and ZEZULKA, L. and FANDRÉ, P. and SCHMID, F. and SPOLENAK, R.",
  title="Nanodroplet Flight Control in Electrohydrodynamic Redox 3D Printing",
  journal="ACS APPL MATER INTER",
  year="2023",
  volume="16",
  number="1",
  pages="1283--1292",
  doi="10.1021/acsami.3c10829",
  issn="1944-8244",
  url="https://doi.org/10.1021/acsami.3c10829"
}