Publication detail

Spotlighting the boosted energy storage capacity of CoFe2O4/Graphene nanoribbons: A promising positive electrode material for high-energy-density asymmetric supercapacitor

Xia, Changlei Ren, Tiyao Shabani-Nooshabadi, Mehdi Klemes, Jiri Jaromir Karaman, Ceren Karimi, Fatemeh Wu, Yingji Kamyab, Hesam Vasseghian, Yasser Chelliapan, Shreeshivadasan

Original Title

Spotlighting the boosted energy storage capacity of CoFe2O4/Graphene nanoribbons: A promising positive electrode material for high-energy-density asymmetric supercapacitor

Type

journal article in Web of Science

Language

English

Original Abstract

CoFe2O4/Graphene Nanoribbons (GNRs) nanocomposite was successfully fabricated and utilised as an electrode active material for high-energy supercapacitor cells. Thanks to the outstanding physicochemical features of a graphene nanoribbon with excellent electrical conductivity and the synergistic effect with cobalt ferrite, as well as the pseudocapacitive effect. The CoFe2O4/GNRs nanohybrid offered an exceptional specific capacitance of 922 F g- 1 (415 C g- 1) at 1.0 A g-1 in 3.0 M KOH electrolyte in a standard 3-electrode set-up. Additionally, the impressive supercapacitive performance metrics showed that the suggested electrode had a distinctive morphology and could be a candidate for capacitive energy storage systems. These metrics included good cycle stability and 87% capacitance retention at the end of the 10,000th CV cycle. Moreover, the asymmetric supercapacitor cell (ASC) was designed by assembling CoFe2O4/GNRs and activated carbon (AC). The resultant ASC provided an improved specific capacitance of 487.85 F g- 1 (683 C g-1) at 1.0 A g-1. At this current density value, the energy density and the power density values were computed as to be 132.8 Wh.kg- 1 and 632.39 W kg- 1. The highest power density was discovered to be 6730.76 W kg- 1 at 10.0 A g-1, whereas the energy density was determined as 8.75 Wh.kg- 1 at this current density. The results of the work proved that CoFe2O4/GNRs nanohybrids are up-and-coming electrode active materials for advanced electrochemical energy storage and conversion technologies.

Keywords

Asymmetric supercapacitor; CoFe2O4/Graphene nanoribbon; Electrochemical activity; Energy storage systems; High-energy density; Hybrid electrodes

Authors

Xia, Changlei; Ren, Tiyao; Shabani-Nooshabadi, Mehdi; Klemes, Jiri Jaromir; Karaman, Ceren; Karimi, Fatemeh; Wu, Yingji; Kamyab, Hesam; Vasseghian, Yasser; Chelliapan, Shreeshivadasan

Released

1. 5. 2023

Publisher

PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

Location

PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

ISBN

0360-5442

Periodical

Energy

Year of study

270

Number

1

State

United Kingdom of Great Britain and Northern Ireland

Pages count

13

URL

https://www.sciencedirect.com/science/article/pii/S0360544223003080?via%3Dihub

BibTex

@article{BUT187460,
  author="Xia, Changlei and Ren, Tiyao and Shabani-Nooshabadi, Mehdi and Klemes, Jiri Jaromir and Karaman, Ceren and Karimi, Fatemeh and Wu, Yingji and Kamyab, Hesam and Vasseghian, Yasser and Chelliapan, Shreeshivadasan",
  title="Spotlighting the boosted energy storage capacity of CoFe2O4/Graphene nanoribbons: A promising positive electrode material for high-energy-density asymmetric supercapacitor",
  journal="Energy",
  year="2023",
  volume="270",
  number="1",
  pages="13",
  doi="10.1016/j.energy.2023.126914",
  issn="0360-5442",
  url="https://www.sciencedirect.com/science/article/pii/S0360544223003080?via%3Dihub"
}