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FARKA, D. CIGÁNEK, M. VESELÝ, D. KALINA, L. KRAJČOVIČ, J.
Original Title
Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers
Type
journal article in Web of Science
Language
English
Original Abstract
The anisotropic nature of charge transport through organic materials requires high control over the self-assembly of the organic materials. This is particularly so for conductive polymers, where transport occurs mainly along the polymers' backbone. Herein, we demonstrate the use of self-assembled monolayers (SAMs) to influence the self-assembly of poly(3-adamantylmethylthiophene). We employ two different SAMs, which interact with either the adamantyl- or the thiophene-functionality, respectively, and acquire distinct topologies as compared to the unmodified Au(111) surface. We compare these results with unmodified glass and mica (muscovite) surfaces, which are typically employed in the field of optoelectronics. We prove the usefulness and applicability of epitaxial effects and adamantyl substituents for organic electronics. This presents a viable way toward improved electronic performance for the field as a whole.
Keywords
Self-assembly; adamantane; monolayers; organic electronics
Authors
FARKA, D.; CIGÁNEK, M.; VESELÝ, D.; KALINA, L.; KRAJČOVIČ, J.
Released
3. 9. 2024
Publisher
AMER CHEMICAL SOC
Location
WASHINGTON
ISBN
2470-1343
Periodical
ACS OMEGA
Year of study
9
Number
37
State
United States of America
Pages from
38733
Pages to
38742
Pages count
10
URL
https://pubs.acs.org/doi/full/10.1021/acsomega.4c04616
BibTex
@article{BUT189619, author="FARKA, D. and CIGÁNEK, M. and VESELÝ, D. and KALINA, L. and KRAJČOVIČ, J.", title="Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers", journal="ACS OMEGA", year="2024", volume="9", number="37", pages="38733--38742", doi="10.1021/acsomega.4c04616", issn="2470-1343", url="https://pubs.acs.org/doi/full/10.1021/acsomega.4c04616" }