Publication detail

Porous Hybrid PVDF/BiFeO3 Smart Composite with Magnetic, Piezophotocatalytic, and Light-Emission Properties

Farid Orudzhev,Nariman Alikhanov,Abdulkarim Amirov,Alina Rabadanova,Daud Selimov,Abdulatip Shuaibov,Rashid Gulakhmedov ,Magomed Abdurakhmanov,Asiyat Magomedova,Shikhgasan Ramazanov,Dinara Sobola ,Kamal Giraev,Akhmed Amirov,Kamil Rabadanov,Sultanakhmed Gadzhimagomedov, Rabadanov Murtazali, Valeria Rodionova

Original Title

Porous Hybrid PVDF/BiFeO3 Smart Composite with Magnetic, Piezophotocatalytic, and Light-Emission Properties

Type

journal article in Web of Science

Language

English

Original Abstract

The creation of multi-stimuli-sensitive composite polymer–inorganic materials is a practical scientific task. The combination of photoactive magneto-piezoelectric nanomaterials and ferroelectric polymers offers new properties that can help solve environmental and energy problems. Using the doctor blade casting method with the thermally induced phase separation (TIPS) technique, we synthesized a hybrid polymer–inorganic nanocomposite porous membrane based on polyvinylidene fluoride (PVDF) and bismuth ferrite (BiFeO3/BFO). We studied the samples using transmission and scanning electron microscopy (TEM/SEM), infrared Fourier spectroscopy (FTIR), total transmission and diffuse reflection, fluorescence microscopy, photoluminescence (PL), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), vibrating-sample magnetometer (VSM), and piezopotential measurements. Our results demonstrate that the addition of BFO increases the proportion of the polar phase from 76.2% to 93.8% due to surface ion–dipole interaction. We also found that the sample exhibits laser-induced fluorescence, with maxima at 475 and 665 nm depending on the presence of nanoparticles in the polymer matrix. Furthermore, our piezo-photocatalytic experiments showed that under the combined actions of ultrasonic treatment and UV–visible light irradiation, the reaction rate increased by factors of 68, 13, 4.2, and 1.6 compared to sonolysis, photolysis, piezocatalysis, and photocatalysis, respectively. This behavior is explained by the piezoelectric potential and the narrowing of the band gap of the composite due to the mechanical stress caused by ultrasound.

Keywords

BiFeO3; PENG; photocatalysis; piezocatalysis; piezophotocatalysis; PVDF; smart materials; ultrasound

Authors

Farid Orudzhev,Nariman Alikhanov,Abdulkarim Amirov,Alina Rabadanova,Daud Selimov,Abdulatip Shuaibov,Rashid Gulakhmedov ,Magomed Abdurakhmanov,Asiyat Magomedova,Shikhgasan Ramazanov,Dinara Sobola ,Kamal Giraev,Akhmed Amirov,Kamil Rabadanov,Sultanakhmed Gadzhimagomedov, Rabadanov Murtazali, Valeria Rodionova

Released

11. 5. 2023

Publisher

MDPI

Location

https://www.mdpi.com/2073-4344/13/5/874

ISBN

2073-4344

Periodical

Catalysts

Year of study

13(5)

Number

874

State

Swiss Confederation

Pages from

1

Pages to

21

Pages count

21

URL

https://www.mdpi.com/2073-4344/13/5/874

BibTex

@article{BUT189752,
  author="Dinara {Sobola} and Farid {Orudzhev} and Nariman {Alikhanov} and Abdulkarim {Amirov} and Alina {Rabadanova} and Daud {Selimov} and Abdulatip {Shuaibov} and Rashid {Gulakhmedov} and Magomed {Abdurakhmanov} and Asiyat {Magomedova} and Shikhgasan {Ramazanov} and Kamal M. {Giraev} and Akhmed {Amirov} and Kamil {Rabadanov} and Sultanakhmed {Kh. Gadzhimagomedov} and Murtazali {Kh. Rabadanov} and Valeria {Rodionova}",
  title="Porous Hybrid PVDF/BiFeO3 Smart Composite with Magnetic, Piezophotocatalytic, and Light-Emission Properties",
  journal="Catalysts",
  year="2023",
  volume="13(5)",
  number="874",
  pages="1--21",
  doi="10.3390/catal13050874",
  issn="2073-4344",
  url="https://www.mdpi.com/2073-4344/13/5/874"
}