Publication detail

Multiscale hierarchical nanoarchitectonics with stereographically 3D-printed electrodes for water splitting and energy storage

SUBHADARSHINI, S. GHOSH, K. PUMERA, M.

Original Title

Multiscale hierarchical nanoarchitectonics with stereographically 3D-printed electrodes for water splitting and energy storage

Type

journal article in Web of Science

Language

English

Original Abstract

The pursuit of sustainable solutions to address the global energy crisis has led to a keen interest in the advancement of cost-effective and multifunctional electrochemical systems. These systems aim to achieve both zero -carbon emissions and the dual capability to convert and store energy ef ficiently. The electrochemical splitting of water is one way to create carbon -neutral, clean hydrogen gas. Electrocatalysis and hydrogen evolution in general depends not only on the catalyst but also on its nano- and microstructure, which in fluences local chemical conditions and hydrogen gas bubble detachment. Therefore, rapid screening of not only potential catalysts but also various structured surfaces is needed for effective electrode fabrication. The fused deposition modeling (FDM) method of 3D printing is frequently used for electrode fabrication using conducting filaments; however, its micro-structuration resolution is limited. Stereolithography can produce complex and fine structures; however, the resins are not conductive and therefore the structures are not suitable for electrode fabrication. In this work, we have fabricated a substrate with highresolution needle array architecture using stereolithographic (SLA) 3D printing and coated it with Co 3 Te 4 - CoTe 2 (COT) nano fiber for water splitting and energy storage. The SLA 3D -printed cobalt telluride electrodes showed appreciable performance as a photoelectrocatalyst for the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER), acting as a bifunctional catalyst. We also demonstrated fabrication of a cobalt telluride based SLA 3D -printed supercapacitor device with multiscale hierarchy. The SLA 3D -printed supercapacitor device exhibited good electrochemical behavior along with high cycling stability. In general, we show here a universal method for SLA conductive electrode fabrication with hierarchical structuring of functional elements and suitable for various applications.

Keywords

Stereolithography; 3D Printing; Energy storage; Energy conversion

Authors

SUBHADARSHINI, S.; GHOSH, K.; PUMERA, M.

Released

1. 5. 2024

Publisher

ELSEVIER SCI LTD

Location

London

ISBN

1873-4103

Periodical

MATERIALS TODAY

Year of study

74

Number

1

State

United Kingdom of Great Britain and Northern Ireland

Pages from

34

Pages to

45

Pages count

12

URL

https://www.sciencedirect.com/science/article/pii/S1369702124000257?via%3Dihub

BibTex

@article{BUT189997,
  author="Suvani {Subhadarshini} and Kalyan {Ghosh} and Martin {Pumera}",
  title="Multiscale hierarchical nanoarchitectonics with stereographically 3D-printed electrodes for water splitting and energy storage",
  journal="MATERIALS TODAY",
  year="2024",
  volume="74",
  number="1",
  pages="34--45",
  doi="10.1016/j.mattod.2024.02.004",
  issn="1873-4103",
  url="https://www.sciencedirect.com/science/article/pii/S1369702124000257?via%3Dihub"
}