Publication detail

Application of isothermal and isoperibolic calorimetry to assess the effect of zinc on cement hydration

ŠILER, P. KOLÁŘOVÁ, I. NOVOTNÝ, R. MÁSILKO, J. POŘÍZKA, J. BEDNÁREK, J. ŠVEC, J. OPRAVIL, T.

Original Title

Application of isothermal and isoperibolic calorimetry to assess the effect of zinc on cement hydration

Type

journal article in Web of Science

Language

English

Original Abstract

The aim of this work was to determine the effect of zinc on Portland cement hydration. This effect was studied by isothermal and isoperibolic calorimetry. Both calorimetry methods are suitable for measurements during the first days of hydration. Isoperibolic calorimetry monitors hydration process in real-life conditions, while isothermal calorimetry does it at a defined chosen temperature. Zinc was added to the cement in the form of two soluble salts of Zn(NO3)2, ZnCl2 and a poorly soluble compound ZnO. The concentration of zinc added was chosen as 0.05, 0.1, 0.5 and 1 mass%. The results show that increasing amounts of zinc ions in cement pastes lead to hydration retardation and reduce both the maximum temperature and the maximum heat flow due to the retarding effect of zinc. The newly formed compounds during hydration were identified by X-ray diffraction method.

Keywords

Portland cement; Zinc; Isothermal calorimetry; Isoperibolic calorimetry; Hydration

Authors

ŠILER, P.; KOLÁŘOVÁ, I.; NOVOTNÝ, R.; MÁSILKO, J.; POŘÍZKA, J.; BEDNÁREK, J.; ŠVEC, J.; OPRAVIL, T.

Released

1. 7. 2018

Publisher

Springer

Location

Maďarsko

ISBN

1388-6150

Periodical

Journal of Thermal Analysis and Calorimetry

Number

133

State

Hungary

Pages from

27

Pages to

40

Pages count

14

URL

https://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=3&SID=E5kZz6kraH6kqusUVGZ&page=1&doc=1

BibTex

@article{BUT151390,
  author="Pavel {Šiler} and Iva {Šilerová} and Radoslav {Novotný} and Jiří {Másilko} and Jaromír {Pořízka} and Jan {Bednárek} and Jiří {Švec} and Tomáš {Opravil}",
  title="Application of isothermal and isoperibolic calorimetry to assess the effect of zinc on cement hydration",
  journal="Journal of Thermal Analysis and Calorimetry",
  year="2018",
  number="133",
  pages="27--40",
  doi="10.1007/s10973-017-6815-1",
  issn="1388-6150",
  url="https://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=3&SID=E5kZz6kraH6kqusUVGZ&page=1&doc=1"
}