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LEPCIO, P. ONDREÁŠ, F. ZÁRYBNICKÁ, K. ZBONČÁK, M. SVATÍK, J. JANČÁŘ, J.
Original Title
Phase diagram of bare particles in polymer nanocomposites: Uniting solution and melt blending
Type
journal article in Web of Science
Language
English
Original Abstract
Nanoparticle (NP) spatial arrangement in polymer matrix is a widely investigated scientific issue of great practical importance. The structure of polymer nanocomposites (PNCs) with bare non-grafted NPs are usually evaluated separately for blending in polymer melt and in polymer solution. To the best of our knowledge, no theory of PNC structure has successfully integrated all aspects of solution blending yet, let alone brought a direct comparison of PNC structures prepared by melt and solution blending. In the current study, we for the first time implement the role of solvent into the existing PRISM theory for nanoparticle ordering in polymer melts, compare the theoretical prediction to experimentally prepared structures, and present a united phase diagram for both melt and solution blended PNCs with bare non-grafted NPs.
Keywords
Structure; Polymer nanocomposite; Phase diagram
Authors
LEPCIO, P.; ONDREÁŠ, F.; ZÁRYBNICKÁ, K.; ZBONČÁK, M.; SVATÍK, J.; JANČÁŘ, J.
Released
16. 9. 2021
Publisher
Elsevier Ltd
ISBN
0032-3861
Periodical
Polymer
Year of study
230
Number
124033
State
United Kingdom of Great Britain and Northern Ireland
Pages from
Pages to
Pages count
6
URL
https://www.sciencedirect.com/science/article/pii/S003238612100656X
BibTex
@article{BUT172299, author="Petr {Lepcio} and František {Ondreáš} and Klára {Zárybnická} and Marek {Zbončák} and Juraj {Svatík} and Josef {Jančář}", title="Phase diagram of bare particles in polymer nanocomposites: Uniting solution and melt blending", journal="Polymer", year="2021", volume="230", number="124033", pages="124033--124033", doi="10.1016/j.polymer.2021.124033", issn="0032-3861", url="https://www.sciencedirect.com/science/article/pii/S003238612100656X" }