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BARTLOVÁ, M., BARTL, J., COUFAL, O.
Original Title
Unimolecular Reactions in Chemical Kinetics of SF6-Arc Plasma
Type
conference paper
Language
English
Original Abstract
Rate constants of unimolecular dissociation of molecules SF6 , SF5 , SF4 , SF3 ,SF2 have been computed by means of Kassel integrals interpolating both the values of low pressure and high pressure limits. The collision theory has been used for determination of low pressure rate constants , high pressure rate constants have been calculated by statistical adiabatic channel model. We have used obtained values to the study of the influence of different values of reaction rate constants on the kinetic composition of the SF6 system during the extinction process in the switching arc.
Key words in English
Rateconstants, unimolecular dissociation, kinetic composition, arc plasma
Authors
RIV year
2003
Released
5. 1. 2003
Publisher
Dept. of Plasma Physics & Institute of Physics at Comenius University
Location
Bratislava
ISBN
80-8040-195-0
Book
Proceedings of the XIVth Symposium on Application of Plasma Processes
Pages from
12
Pages to
17
Pages count
6
BibTex
@inproceedings{BUT8898, author="Milada {Bartlová} and Josef {Bartl} and Oldřich {Coufal}", title="Unimolecular Reactions in Chemical Kinetics of SF6-Arc Plasma", booktitle="Proceedings of the XIVth Symposium on Application of Plasma Processes", year="2003", pages="6", publisher="Dept. of Plasma Physics & Institute of Physics at Comenius University", address="Bratislava", isbn="80-8040-195-0" }