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FCH-BCO_SVMAcad. year: 2014/2015
Structural levels in the macromolecular systems. Molecular weight and weight distributions. Polydispersity and average molecular weights. Relationships between molecular weight and properties of solid polymers. Polymer constitution, configuration and conformation. Linear, branched and cross-linked macromolecules. Alternating, statistical and block copolymers. Conformers and stereoregularity. Statistical coil. Conformational statistics. Intermolecular interactions. Supermolecular structure, morphology. Mechanism and kinetics of crystallization. Spherolites, dendrites, transcrystallinity. Macromolecules in dilute solutions. Flory-Huggins equation, interaction parameter and solubility parameter. Thermodynamics of polymer mixing, polymer solubility.
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Specification of controlled education, way of implementation and compensation for absences
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branch BPCO_CHM , 3 year of study, winter semester, compulsory
branch BKCO_CHM , 3 year of study, winter semester, compulsory
branch CKCO_CZV , 1 year of study, winter semester, compulsory
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