Czech

Not applicable.

Student will obtain practical knowledge necessary for the application of the quantum mechanics apparatus. He will be friendly with micro and macrosystems behaviour based on the solution of electronic strucure of the atoms and molecules solved by the quantum mechanics basic principles.

Basic mathematics - diferentials and integrals
Basic physics - mass point motion, electrostatic field

Not applicable.

The course uses teaching methods in form of Lecture - 2 teaching hours per week, Seminar - 2 teaching hours per week. The e-learning system (LMS Moodle) is available to teachers and students.

Written test contains 7 basic quantum mechanics problems as well as the applications. The overview through whole quantum mechanics fundaments is a subject of the spoken part of examen, especially with respect to the causal connections.

1. Quantum mechanics necessity. Black body radiation. Caloric capacity of solids. Photoelectric phenomenon. Compton phenomenon. Stability of atoms and electronic spectra interpretation. Spectral lines splitting in the electric and magnetic fields.

2. Elementary basis of the quantum mechanics. Operators and their characteristic values.

3. Quantum mechanics postulates. Heisenberg principle of uncertainty.

4. Simple quantum mechanic systems. Particle in the potential hollow. Tunnel effect.

5. Linear harmonic oscillator.

6. Spherical coordinate system. Rigid rotator.

7. Hydrogen atom.

8. Moment of movement in the quantum mechanics and its properties.

9. Orbital and spin moments. Combining of the moments.

10. Electronic structure of atoms. Many particle problem in quantum mechanics. Permutation operators. Slater determinant. Pauli's exclusion principle. Electronic configuration of atoms and atomic terms.

11. Chemical bound. H2+ molecular ion. Heilter-London model of H2 molecule.

12. Born-Oppenheimer approximation. Molecular orbitals. LCAO MO approximation. Localized and delocalized molecular orbitals. Hybridization.

13. VSEPR method and molecular geometry. Crystal field theory. Chemical bound in solids. Semi empiric methods of molecular orbitals.

Not applicable.

The course gives the basic knowledge of processes in microcosm and their reflection observable in the material structure. The second part is focused on the microcosm reflections in macroscopic systems.

none

Not applicable.

Not applicable.

Pelikán P., Lapčík L., Zmeškal O., Krčma F.: Fyzikální chemie, Struktura hmoty. VUTIUM Brno, Brno 2000. (CS)
Zahradník R., Polák R.: Základy kvantové chemie. SNTL, Praha 1985. (CS)

Atkins P. W., Friedman R.: Molecular Quantum Mechanics. Oxford University Press, Oxford 2005. (CS)
Atkins P. W.: Physical Chemistry. Oxford University Press, Oxford 2006. (CS)