Czech

Not applicable.

Students will be able to use the acquired knowledge in the following master studies of material engineering and to the solution of appropriate problems of industrial practice.

The knowledge of inorganic, organic and physical chemistry on the secondary school level or basic course of chemistry of mechanical engineering is assumed.

Not applicable.

The course is taught through lectures explaining the basic principles and theory of the discipline. Teaching is suplemented by practical laboratory work.

Course-unit credit requirements: attendance at seminars and fulfilment of assignments. Examination verifies the knowledge of the theory and its applications to solving practical problems. The exam consists of written and oral parts; students take the oral exam even though they do not succeed in the written part.

Lecture 13 x 2 hrs.
seminars 13 x 1 hrs.

Lecture

1. Polymers: monomers, nomenclature of polymers, polymerisation stage, functionality of monomers, structure of polymers.
2. Chain polymerisation: influence of chemical structure of monomer on polymerisation mechanism, iniciation-propagation-termination-chain transfer; radical, ionic and coordination polymerisation, copolymerisation.
3. Polycondensation polymerisation: influence of monomers structure on polycondensation, mechanisms of poolycondensation.
4. Polyadition: mechanism of polyaditio, block and grafted copolymers. Reaction of polymers: netting of polymers, degradation of polymers.
5. Ceramic powders: conventional preparation method, homogeneous and heterogeneous nucleation, particle growth in solution, coprecipitation.
6. Ceramic powders: sol-gel synthesis of colloids, sol-gel processing of metalorganic compounds, polycondensation sol-gel methods.
7. Ceramic powders: non-conventional preparation methods-hydrothermal, microwave and sonochemical methods, hydrolysis of salt solutions, non-aqeous liquid-phase reactions.
8. Gas-phase syntheses. Aerosol-derived powders. Emulsion reactions of powders. Freeze- and spray- drying.
9. Polymerisation methods of ceramic synthesis: Synthesis of organometallic polymers. Polymer pyrolysis. Synthesis of non-oxide particles.
10. Biomimetic methods: natural ceramic materials and their formation by biological ways. Biomimetic pricessing of bioceramic.
11. Colloids-attractive forces between colloidal particles. Classification of physical forces. Van der Waals forces. Interaction between surfaces and particles. Hamaker constant.
12. Colloids-electrostatic forces and the electrical double layer: sources of interfacial charge. Electrostatic theory- Coulombś law. Electrokinetic phenomena.
13. Colloids and Colloidal stability: Colloid structure. Stability of colloids and mechanisms of stabilization-electrostatic and steric stabilization. DLVO theory. Coagulation of colloids.

seminars in computer labs
1. Polymers
2. Chain polymerisation
3. Polycondensation polymerisation
4. Polyadition
5. Ceramic powders: conventional preparation method
6. Ceramic powders: non-conventional preparation methods
7. Polymerisation methods of ceramic synthesis
8. Gas-phase syntheses. Aerosol-derived powders. Emulsion reactions of powders
9. Polymerisation methods of ceramic synthesis
10. Biomimetic methods
11. Colloids-attractive forces between colloidal particles
12. Colloids-electrostatic forces and the electrical double layer
13. Colloids and Colloidal stability

Not applicable.

The aim of the course is to provide the students of material engineering fundamental physical and chemical information about synthesis of non-metallic materials and their precursors, which are important for understanding the relations between the structure of materials end their (physical) chemical reactivity.

Attendance at seminars and fulfilment of assignments is required. In case students do not meet these conditions they can be given additional assignments.

Not applicable.

Not applicable.

B.I. Lee and E.J.A. Pope (editor): Chemical Processing of Ceramics, Marcel Pokker, New York 1994, p.61-127.
B.J. Brook (editor): Processing of Ceramics, Part II., vol. 178 of Materials Science and Technology, Wiley-WCH, Weinheim 1996, p.2-82.
D. Myers: Surfaces, Interfaces, and Colloids, Wiley-WCH, New York 1999.
L.V. Interrante and M.J. Hampden-Smith (editor), Chemistry of Advanced Materials, Wiley-WCH, New York 1998, p.389-448.
M. Kučera: Vznik makromolekul I., Vysoké učení technické v Brně, nakladatelství VUTIUM, 2003.
M. Kučera: Vznik makromolekul II., Vysoké učení technické v Brně, nakladatelství VUTIUM, 2003.
R.J. Brook (editor): Processing of Ceramics, Part I., vol 17A of Materials Science and technology, Wiley – WCH, Weinheim 1996, p.70-98.

B.J. Brook (editor): Processing of Ceramics, Part II., vol. 178 of Materials Science and Technology, Wiley-WCH, Weinheim 1996, p.2-82.
D. Myers: Surfaces, Interfaces, and Colloids, Wiley-WCH, New York 1999.
M. Kučera: Vznik makromolekul I., Vysoké učení technické v Brně, nakladatelství VUTIUM, 2003.
M. Kučera: Vznik makromolekul II., Vysoké učení technické v Brně, nakladatelství VUTIUM, 2003.
R.J. Brook (editor): Processing of Ceramics, Part I., vol 17A of Materials Science and technology, Wiley – WCH, Weinheim 1996, p.70-98.