Czech

Not applicable.

Students will be able to use the acquired knowledge in the related master studies of material engineering and apply it to the solution of appropriate problems of industrial practice particularly the problems connected with the selection of special structural materials.

Knowledge of physics, chemical thermodynamics and kinetics and also synthesis of ceramics on the level of introductory university courses is assumed.

Not applicable.

The course is taught through lectures explaining the basic principles and theory of the discipline. Teaching is suplemented by practical laboratory work.

Course-unit credit requirements: attendance at seminars and fulfilment of assignments. Examination verifies the knowledge of the theory and its applications to solving practical problems. The exam consists of written and oral parts; students take the oral exam even though they do not succeed in the written part.

Lecture 13 x 3 hrs.
labs and studios 13 x 1 hrs.

Lecture 1. Bonding in ceramics - Structure of atoms. Ionically bonded solids. Covalently bonded solids. Band theory of the solids
2. Structure of crystalline ceramics – Crystal structures. Binary ionic compounds. Composite crystal structures. Structure of covalent ceramics
3. Structure of glass ceramics – Glass formation. Models of glass structure. Structure of oxide glasses
4. Structural imperfections – Point defects: stoichiometric, nonstoichiometric, intrinsic. Notation of point defects. Linear defects. Planar defects
5. Solid-state reactions in ceramics – Kinetics of heterogeneous reactions. Electrochemical potential in ionic solids. Liquid-solid reactions. Powder reactions. Precipitation in crystalline ceramics
6. Microstructure of ceramics – Characteristics of microstructure. Quantitative analysis. Typical microstructures: advanced ceramics, glasses, glass-ceramics
7. Thermal properties – Thermal stresses. Thermal shock. Microcracking of ceramics. Thermal tempering of glass. Thermal conductivity
8. Mechanical properties - Strength of ceramics. Fracture toughness. Toughening mechanisms. Designing with ceramics. Creep, subcritical crack growth. Fatigue of ceramics
9. Dielectric properties – Basic theory. Polarisation mechanisms. Dielectric loss. Capacitors and insulators
10. Magnetic properties – Basic theory. Para-, ferro-, antiferro- and ferrimagnetisms. Magnetic domains and hysteresis curve. Magnetic ceramics
11. Electrical conductivity in ceramics – Diffusion and conductivity. Ionic conductivity. Electronic conductivity. Solid state galvanic cells
12. Optical properties – Basic principles. Absorption and transmission. Scattering and opacity
13. Applications of ceramics – Engineering ceramics. Electroceramics. Bioceramics

labs and studios
1. Lattice energy, Madelung constant, ionisation energy and fracture ionic characters, coordination number
2. Structure of crystalline and glass ceramics
3. Reactions controlled by diffusion, rate of chemical reaction, activation energy
4. Thermal and mechanical properties of ceramics
5. Diffusion and electrical properties of ceramics
6. Dielectric, magnetic and optical properties of ceramics
Ceramographic analysis of typical ceramic microstructures:
7. Preparation of samples for analysis (cutting, compounding)
8. Preparation of samples for analysis (polishing)
9. Preparation of samples for analysis (thermal etching)
10. Optical microscopy
11. Electronic microscopy
12. Quantitative ceramographic analysis
13. Elaboration of test report

Not applicable.

The objective of the course is to make students familiar with the fundamentals of ceramic material science from the viewpoint of structure-properties relations.

Attendance at all practical lessons and fulfilment of assignments is required. In case students do not meet these conditions they can be given additional assignments.

Not applicable.

Not applicable.

D. Halliday, R. Resnick, J. Walker: Fyzika, Část 2: Mechanika – Termodynamika, VUTIUM, Brno 2000 (CS)
D.W.Richerson: Modern Ceramic Engineering,Marcel Dekker,New York 1992 (EN)
J. Cihlář: Chemie slévárenských materiálů, Nakladatelství VUT v Brně, 1991 (CS)
M.W.Barsoum: Fundamentals of Ceramics, IOP Publishing, London 2003 (EN)
V. Šatava: Úvod do Fyzikální Chemie Silikátů: SNTL, Praha, 1965 (CS)
W.D.Kingery, H.K.Bowen and D.R. Uhlmann: Introduction to Ceramics,Wiley, New York 1976 (EN)

J. Cihlář: Chemie slévárenských materiálů, Nakladatelství VUT v Brně, 1991 (CS)
D. Halliday, R. Resnick, J. Walker: Fyzika, Část 2: Mechanika – Termodynamika, VUTIUM, Brno 2000 (CS)
M.W.Barsoum: Fundamentals of Ceramics, IOP Publishing, London 2003
W.D.Kingery, H.K.Bowen and D.R. Uhlmann: Introduction to Ceramics,Wiley, New York 1976