Czech

Not applicable.

Students will know principles of spectroscopy, construction and use of spectrometers and application of various spectroscopic methods in chemical practice.

Physical chemistry III
Physics - optics

Not applicable.

The course uses teaching methods in form of Lecture - 2 teaching hours per week. The e-learning system (LMS Moodle) is available to teachers and students.

Written part will consist from 7 spectroscopic calculations, spoken part will be focused on overwiev and crosslinks

1. Atomic and molecular energetic levels. Electromagnetic radiation and spectral transitions. Absorption of electromagnetic radiation

2. Atomic spectroscopy. Spectral line profile

3. Rotational spectra. Centrifugal distortion. Raman scattering

4. Vibrational spectra. Anharmonicity of vibrations

5. Vibrational-rotational spectra of diatomic molecules. Vibrations of polyatomic molecules. Group vibrations

6. Electron spectroscopy. Franck-Condon principle. Selection rules for the electronic transitions. Fluorescence and phosphorescence. Photoelectron spectroscopy

7. Spectrometers - contruction, prisms, gratings, resolution

8. Light sources

9. Lasers

10. Detectors and accessories

11. Spectroscopic methods actually used in chemistry - IR, FT-IR, ICP, AAS, LIBS, LIF, TALIF, fluorimetry etc.

12. Magnetic resonance methods. EPR and NMR

13. Methods that will be introduced in near future - Cavity Ring Down, laser tomography, etc.

Not applicable.

The goal of course is to give the overview of spectroscopic methods based on quantum mechanics, spectrometric equipment and the actually used methods in chemistry.

none

Not applicable.

Not applicable.

Atkins P. W.: Physical Chemistry. Oxford University Press, Oxford 2006. (CS)
Pelikán P., Lapčík L., Zmeškal O., Krčma F.: Fyzikální chemie, Struktura hmoty. VUTIUM Brno, Brno 2000. (CS)

Hollas J. M.: Modern Spectroscopy. Wiley, Chichester 1987. (CS)