Course detail
Chemical Thermodynamics and Kinetics
FSI-WCTAcad. year: 2024/2025
Course deals with basic terms, principles and relations of classical chemical thermodynamics and kinetics, which are necessary for understanding of physical-chemical problems of material science. Chemical thermodynamics is focused on basic thermodynamic principles, variables and relations, description of equilibrium in single- and multi-component homogenous and heterogeneous systems, and on phase diagrams. Multi-component chemical reactive systems and problem of capillarity are also mentioned.
Kinetics shows basic kinetic philosophy of physical-chemical processes in heterogeneous systems, particularly phase transformations diffusion and sintering.
Language of instruction
Number of ECTS credits
Mode of study
Guarantor
Entry knowledge
Rules for evaluation and completion of the course
There will be two written tests during the semester. Student has to be classified better than F at both tests. The assistant determines dates of corrective tests.
Examination verifies the knowledge of the theory and particularly its application. It contains written and oral parts. Examiner assesses the relative importance of oral and written parts of the exam, he can take into account student’s activity during the semester. The examiner has to familiarize students (at the latest during the last lecture) with the course of examination and with the principles of classification
Attendance at all practical lessons and fulfilment of assignments are required. In case that students do not meet these conditions they can be given additional assignments.
Aims
Students will obtain basic knowledge of classical chemical thermodynamics and kinetics of selected engineering processes, and will understand their logic and how to apply them for solution of engineering tasks aided by literature sources and databases.
Study aids
Prerequisites and corequisites
Basic literature
R. T. De Hoff: Thermodynamics in Materials Science, McGraw Hill, New York 1993 (EN)
W. J. . Moore, Fyzikální chemie, SNTL, Praha 1979 (CS)
Recommended reading
Classification of course in study plans
Type of course unit
Lecture
Teacher / Lecturer
Syllabus
OUTLINE
1.Structure of chemical thermodynamics. Classification of thermodynamic systems, variables and relations. Equilibrium criteria.
2. Thermodynamics principles. 1st, 2nd and 3rd thermodynamic principle.
3. Thermodynamic relations and variables. General strategy of thermodynamic relations derivation.
4. Equilibrium in thermodynamic systems. General criteria and general conditions of thermodynamic equilibrium derivation. Gibbs phase rule.
5. Single-component heterogeneous system. Single-component phase diagrams in (p,T) range. Clausius-Clapeyron equation.
6. Multi-component, homogenous non-reactive systems – solutions. Partial molar quantities. Chemical potential in multi-component systems.
7. Multi-component heterogeneous non-reactive systems. Description of multi-phase, multi-component, non-reactive systems. Ideal solutions, Raoult’s law. Equilibrium criteria.
8. Multi-component, multi-phase, reactive systems. Reactions in multi-phase systems. Components and compounds in phase diagrams. Van’t Hoffs isotherm and its application in materials engineering.
9. Equilibrium criteria in systems with curved surfaces. Capillary effects. Surfaces and inter-surfaces. Grain boundaries.
10. Kinetics and dynamics of solid-state processes. Transport in solid substances. Diffusion. Activation energy of diffusion.
11. Sintering and grain growth. Solid-state sintering. Liquid phase sintering. Sintering models.
12. Sintering and grain growth. Pressure-activated sintering. Grain growth.
13. Summary of topics for the exam.
Laboratory exercise
Teacher / Lecturer
Syllabus
1. Laboratory work - FME
2. Laboratory work - CEITEC
Computer-assisted exercise
Teacher / Lecturer
Syllabus
- Introductory written test, chemical terminology
- Chemical equations, calculations according to chemical equations
- Redox reactions
- Thermochemistry – heat capacity, reaction heat
- Thermochemistry – temperature dependence of reaction heat
- First written test
- Dependence of Gibbs energy on temperature
- Clapeyron, Clausius-Clapeyron equation
- Systems with multiple components, expression of composition
- Surface energy, Laplace’s law
- Second written test