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FCH-MA_FCDAcad. year: 2024/2025
Classification and properties of disperse systems: kinetic and dynamic properties of disperse systems.Thermal motion dynamics and consequences: osmosis, diffusion, concentration fluctuations. Sedimentation and sedimentation analysis. Viscosity of disperse systems. Elastic light scattering, quasi-elastic light scattering. Macromolecular systems: classifiacation, configuration and stereoregularity.Conformation statistics, freely-rotating chain, freely-jointed chain, constrained chain, equivalent chain, persistent length of chain, domain of macromolecule clusters. Thermodynamics of polymer solutions, combinatoric entropy and enthalpy of mixing, Flory-Huggins equation, interaction parameter.Phase behavior of polymer solutions, the critical dissolving temperature, the critical composition.Diluted polymer solutions, random coil conformation, Flory-Fox equation, hydrodynamic properties of polymer solutions, osmotic pressure.Polyelectrolytes: conformation, electrostatic effects, the ionic atmosphere, membrane and osmotic equilibria.Macromolecular gels, covalently crosslinked polymers, gelation, ionogenic gels, swelling behavior, thermodynamics of elasticity, rheological properties, physically crosslinked polymers.
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specialization BF , 1 year of study, summer semester, compulsoryspecialization CHBL , 1 year of study, summer semester, compulsory-optional
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