Detail publikace

Comparison of complexation properties of humic acids and simple organic ligands

KLUČÁKOVÁ, M. BACHRATÁ, R. KARGEROVÁ, A.

Originální název

Comparison of complexation properties of humic acids and simple organic ligands

Typ

článek v časopise - ostatní, Jost

Jazyk

angličtina

Originální abstrakt

Simple organic compounds as citric acid, phthalic acid, salicylic acid, EDTA, hydroquinone and pyrocatechol were used as structural models of active sites of humic acids. Combination of high resolution ultrasound spectrometry with potentiometry, conductometry and UV/VIS spectrometry were utilized for complexation of copper(II) ions by humic acids and model compounds. Changes in the slope of measured quantities were used to find the saturation of binding. Ultrasound spectrometry showed follow changes of hydration of interacting species. The differences observed for individual model compounds show that there are active centres not only with various strength and stability of formed complexes but also with their various rigidity and ability of conformational changes.

Klíčová slova

humic acids, complexation, conformational changes, copper ions

Autoři

KLUČÁKOVÁ, M.; BACHRATÁ, R.; KARGEROVÁ, A.

Rok RIV

2010

Vydáno

1. 12. 2010

Nakladatel

SEVAS Publishing

Místo

Greenville

ISSN

0974-2328

Periodikum

Journal of Biochemical Technology

Ročník

2

Číslo

5

Stát

Spojené státy americké

Strany od

104

Strany do

105

Strany počet

2

BibTex

@article{BUT106106,
  author="KLUČÁKOVÁ, M. and BACHRATÁ, R. and KARGEROVÁ, A.",
  title="Comparison of complexation properties of humic acids and simple organic ligands",
  journal="Journal of Biochemical Technology",
  year="2010",
  volume="2",
  number="5",
  pages="104--105",
  issn="0974-2328"
}