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Annanouchm F. E. Zouhair, H. VALLEJOS VARGAS, S Umek, P. Guttmann, P. Bittencourt, C. Llobet, E.
Originální název
Aerosol-assisted CVD-grown WO3 nanoneedles decorated with copper oxide nanoparticles for the selective and humidity-resilient detection of H2S
Typ
článek v časopise ve Web of Science, Jimp
Jazyk
angličtina
Originální abstrakt
A gas-sensitive hybrid material consisting of Cu2O nanoparticle-decorated WO3 nanoneedles is successfully grown for the first time in a single step via aerosol-assisted chemical vapor deposition. Morphological, structural, and composition analyses show that our method is effective for growing single-crystalline, n-type WO3 nanoneedles decorated with p-type Cu2O nanoparticles at moderate temperatures (i.e., 380 °C), with cost effectiveness and short fabrication times, directly onto microhot plate transducer arrays with the view of obtaining gas sensors. The gas-sensing studies performed show that this hybrid nanomaterial has excellent sensitivity and selectivity to hydrogen sulfide (7-fold increase in response compared with that of pristine WO3 nanoneedles) and a low detection limit (below 300 ppb of H2S), together with unprecedented fast response times (2 s) and high immunity to changes in the background humidity. These superior properties arise because of the multiple p-n heterojunctions created at the nanoscale in our hybrid nanomaterial.
Klíčová slova
aerosol-assisted CVD; functionalization; gas sensor; nanoneedles; nanoparticles
Autoři
Annanouchm F. E.; Zouhair, H.; VALLEJOS VARGAS, S; Umek, P.; Guttmann, P.; Bittencourt, C.; Llobet, E.
Rok RIV
2015
Vydáno
1. 4. 2015
Nakladatel
American Chemical Society
ISSN
1944-8252
Periodikum
ACS applied materials & interfaces
Ročník
7
Číslo
12
Stát
Spojené státy americké
Strany od
6842
Strany do
6851
Strany počet
URL
http://pubs.acs.org/doi/abs/10.1021/acsami.5b00411
BibTex
@article{BUT117970, author="Annanouchm F. E. and Zouhair, H. and VALLEJOS VARGAS, S and Umek, P. and Guttmann, P. and Bittencourt, C. and Llobet, E.", title="Aerosol-assisted CVD-grown WO3 nanoneedles decorated with copper oxide nanoparticles for the selective and humidity-resilient detection of H2S", journal="ACS applied materials & interfaces", year="2015", volume="7", number="12", pages="6842--6851", doi="10.1021/acsami.5b00411", issn="1944-8252", url="http://pubs.acs.org/doi/abs/10.1021/acsami.5b00411" }