Detail publikace

Multivariate classification of echellograms: a new perspective in Laser-Induced Breakdown Spectroscopy analysis

POŘÍZKA, P. KLUS, J. MAŠEK, J. RAJNOHA, M. PROCHAZKA, D. MODLITBOVÁ, P. NOVOTNÝ, J. BURGET, R. NOVOTNÝ, K. KAISER, J.

Originální název

Multivariate classification of echellograms: a new perspective in Laser-Induced Breakdown Spectroscopy analysis

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

In this work, we proposed a new data acquisition approach that significantly improves the repetition rates of Laser-Induced Breakdown Spectroscopy (LIBS) experiments, where high-end echelle spectrometers and intensified detectors are commonly used. The moderate repetition rates of recent LIBS systems are caused by the utilization of intensified detectors and their slow full frame (i.e. echellogram) readout speeds with consequent necessity for echellogram-to-1D spectrum conversion (intensity vs. wavelength). Therefore, we investigated a new methodology where only the most effective pixels of the echellogram were selected and directly used in the LIBS experiments. Such data processing resulted in significant variable down-selection (more than four orders of magnitude). Samples of 50 sedimentary ores samples (distributed in 13 ore types) were analyzed by LIBS system and then classified by linear and non-linear Multivariate Data Analysis algorithms. The utilization of selected pixels from an echellogram yielded increased classification accuracy compared to the utilization of common 1D spectra.

Klíčová slova

Analytical chemistry; Geology; Statistics

Autoři

POŘÍZKA, P.; KLUS, J.; MAŠEK, J.; RAJNOHA, M.; PROCHAZKA, D.; MODLITBOVÁ, P.; NOVOTNÝ, J.; BURGET, R.; NOVOTNÝ, K.; KAISER, J.

Vydáno

1. 12. 2017

Nakladatel

Springer Nature

ISSN

2045-2322

Periodikum

Scientific Reports

Ročník

7

Číslo

3160

Stát

Spojené království Velké Británie a Severního Irska

Strany od

1

Strany do

12

Strany počet

12

URL

https://www.nature.com/articles/s41598-017-03426-0

Plný text v Digitální knihovně

http://hdl.handle.net/11012/69360

BibTex

@article{BUT136910,
  author="Pavel {Pořízka} and Jakub {Klus} and Jan {Mašek} and Martin {Rajnoha} and David {Prochazka} and Pavlína {Modlitbová} and Jan {Novotný} and Radim {Burget} and Karel {Novotný} and Jozef {Kaiser}",
  title="Multivariate classification of echellograms: a new perspective in Laser-Induced Breakdown Spectroscopy analysis",
  journal="Scientific Reports",
  year="2017",
  volume="7",
  number="3160",
  pages="1--12",
  doi="10.1038/s41598-017-03426-0",
  issn="2045-2322",
  url="https://www.nature.com/articles/s41598-017-03426-0"
}