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VEČEŘOVÁ, A. HUDCOVÁ, K. PILAŘOVÁ, I. MASAŘÍK, M. TRNKOVÁ, L.
Originální název
Electrochemical and spectral behaviour of miR-34a-5p
Typ
článek ve sborníku ve WoS nebo Scopus
Jazyk
angličtina
Originální abstrakt
MicroRNAs are a family of small noncoding RNAs, regulating gene expression at the post-transcriptional level and playing a crucial role as potential biomarkers and targets for many types of cancer. Our attention was given to electrochemical and spectral studies of miR-34a-5p, related to head and neck and also prostate cancer. Voltammetric experiments on a hanging mercury drop electrode and circular dichroic spectroscopic experiments in buffer solutions were performed in the range of pH from 3 to 6 and from 3 to 8, respectively. The miRNA and its DNA sequential analogues (miDNA) provided interesting and significantly different results. A comparison of miRNA and both miDNA (U) and (T) showed the effect of substitution of ribose to deoxyribose, and structural diversity of nucleic acids was confirmed by both electrochemical and spectral methods. It emerged that a single substitution of ribose to deoxyribose (equivalent to miRNA -> miDNA (U)) leads on to the formation of a second guanine oxidation peak, and an RNA molecule in contrast to DNA analogues offers circular dichroic spectra of higher variability (indicating more terminal structures) and a more observable dependence on pH in the range of 3-6.
Klíčová slova
miR-34a-5p; Human cancer; Voltammetry; Circular dichroic spectroscopy; Mercury electrode
Autoři
VEČEŘOVÁ, A.; HUDCOVÁ, K.; PILAŘOVÁ, I.; MASAŘÍK, M.; TRNKOVÁ, L.
Vydáno
1. 1. 2016
ISBN
978-80-905221-3-8
Kniha
XXXV. Moderní elektrochemické metody : sborník přednášek mezinárodní odborné konference
ISSN
0026-9247
Periodikum
Monatshefte fuer Chemie
Ročník
147
Číslo
1
Stát
Rakouská republika
Strany od
105
Strany do
110
Strany počet
6
BibTex
@inproceedings{BUT143110, author="Aneta {Večeřová} and Kristýna {Hudcová} and Iveta {Pilařová} and Michal {Masařík} and Libuše {Trnková}", title="Electrochemical and spectral behaviour of miR-34a-5p", booktitle="XXXV. Moderní elektrochemické metody : sborník přednášek mezinárodní odborné konference", year="2016", journal="Monatshefte fuer Chemie", volume="147", number="1", pages="105--110", doi="10.1007/s00706-015-1600-y", isbn="978-80-905221-3-8", issn="0026-9247" }