Detail publikace

Mechanisms and kinetics of CO2 hydrogenation to value-added products: A detailed review on current status and future trends

Saeidi, S. Najari, S. Fazlollahi, F. Nikoo, M.K. Sefidkon, F. Klemeš, J.J. Baxter, L.L.

Originální název

Mechanisms and kinetics of CO2 hydrogenation to value-added products: A detailed review on current status and future trends

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

Global warming, fossil fuel depletion and energy security are driving scientists to investigate the mechanism of hydrocarbons production from CO2 hydrogenation. The need for more comprehensive understanding on mechanism of CO2 hydrogenation to hydrocarbons remains controversial because of the complex reaction mechanism and a large number of involved species. The micro mechanism of CO2 hydrogenation to hydrocarbons has been considered as a possible remedy to fulfill the requirements. This review comprehensively discusses two processes: reverse water gas shift (RWGS) and CO2 hydrogenation to hydrocarbons. The review includes reaction mechanisms and catalyst effects on yields and rates. In addition, the review outlines each of the Fischer-Tropsch (FT) micro mechanisms. The review infers some mechanisms from existing work and proposes a new mechanism that improves several predictions. These mechanisms form the design basis for optimal reactor design

Klíčová slova

Modified Fischer-Tropsch synthesis; Microkinetics; Micromechanism; Enolic mechanism; Carbide mechanism

Autoři

Saeidi, S.; Najari, S.; Fazlollahi, F.; Nikoo, M.K.; Sefidkon, F.; Klemeš, J.J.; Baxter, L.L.

Vydáno

1. 12. 2017

ISSN

1364-0321

Periodikum

RENEWABLE & SUSTAINABLE ENERGY REVIEWS

Číslo

80

Stát

Spojené státy americké

Strany od

1292

Strany do

1311

Strany počet

20

BibTex

@article{BUT145949,
  author="Saeidi, S. and Najari, S. and Fazlollahi, F. and Nikoo, M.K. and Sefidkon, F. and Klemeš, J.J. and Baxter, L.L.",
  title="Mechanisms and kinetics of CO2 hydrogenation to value-added products: A detailed review on current status and future trends",
  journal="RENEWABLE & SUSTAINABLE ENERGY REVIEWS",
  year="2017",
  number="80",
  pages="1292--1311",
  doi="10.1016/j.rser.2017.05.204",
  issn="1364-0321"
}