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CIGÁNEK, M. HEINRICHOVÁ, P. KUČERÍK, J. KRAJČOVIČ, J.
Originální název
Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives
Typ
abstrakt
Jazyk
angličtina
Originální abstrakt
The series of three DPP derivatives was prepared by nucleophilic substitution of 1-(2-bromoethyl)adamantane chains. The main aim of this work was to focus on isolation of all three possible formed products (NN-; N,O- and O,O-alkylated) and investigate their properties. In this work it was discovered that adamantyl chains has a significant role in the crystallinity of O-alkylated derivative. Furthermore, optical properties were investigated for all prepared derivatives, both in solution and in thin layers. The position of alkyl chains in the DPP molecule significantly affected both absorption and fluorescence emission spectra. The thermal stability of N- and O-alkylated derivatives also differed significantly.
Klíčová slova
diketopyrrolopyrrole; asymmetrical alkylation; adamantyl
Autoři
CIGÁNEK, M.; HEINRICHOVÁ, P.; KUČERÍK, J.; KRAJČOVIČ, J.
Vydáno
21. 11. 2019
Nakladatel
Vysoké učení technické v Brně, Fakulta chemická
Místo
Brno
ISBN
978-80-214-5807-9
Kniha
Studentská odborná konference Chemie je život 2019
Edice
první
Strany od
72
Strany do
Strany počet
1
BibTex
@misc{BUT160834, author="Martin {Cigánek} and Patricie {Heinrichová} and Jiří {Kučerík} and Jozef {Krajčovič}", title="Comprehensive Study of Novel Adamantane Asymmetrically-Substituted Diketopyrrolopyrrole Derivatives", booktitle="Studentská odborná konference Chemie je život 2019", year="2019", series="první", pages="72--72", publisher="Vysoké učení technické v Brně, Fakulta chemická", address="Brno", isbn="978-80-214-5807-9", note="abstract" }