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MAYORGA BURREZO, P. MUÑOZ MARTIN, J. ZAORALOVÁ, D. OTYEPKA, M. PUMERA, M.
Originální název
Multiresponsive 2D Ti3C2Tx MXene via Implanting Molecular Properties
Typ
článek v časopise ve Web of Science, Jimp
Jazyk
angličtina
Originální abstrakt
The design and fabrication of active nanomaterials exhibiting multifunctional properties is a must in the socalled global "Fourth Industrial Revolution". In this sense, molecular engineering is a powerful tool to implant original capabilities on a macroscopic scale. Herein, different bio-inspired 2D-MXenes have been developed via a versatile and straightforward synthetic approach. As a proof of concept, Ti3C2Tx MXene has been exploited as a highly sensitive transducing platform for the covalent assembly of active biomolecular architectures (i.e., amino acids). All pivotal properties originated from the anchored targets were proved to be successfully transferred to the resulting bioinspired 2D-MXenes. Appealing applications have been devised for these 2D-MXene prototypes showing (i) chiroptical activity, (ii) fluorescence capabilities, (iii) supramolecular pi-pi interactions, and (iv) stimuli-responsive molecular switchability. Overall, this work demonstrates the fabrication of programmable 2D-MXenes, taking advantage of the inherent characteristics of the implanted (bio)molecular components. Thus, the current bottleneck in the field of 2D-MXenes can be overcome after the significant findings reported here.
Klíčová slova
2D materials; surface engineering; chiral MXene; fluorescence; molecular switches; supramolecular recognition; electronic devices
Autoři
MAYORGA BURREZO, P.; MUÑOZ MARTIN, J.; ZAORALOVÁ, D.; OTYEPKA, M.; PUMERA, M.
Vydáno
22. 6. 2021
Nakladatel
AMER CHEMICAL SOC
Místo
WASHINGTON
ISSN
1936-086X
Periodikum
ACS Nano (e-ISSN)
Ročník
15
Číslo
6
Stát
Spojené státy americké
Strany od
10067
Strany do
10075
Strany počet
9
URL
https://pubs.acs.org/doi/10.1021/acsnano.1c01742
BibTex
@article{BUT172505, author="Paula {Mayorga Burrezo} and Jose Maria {Muñoz Martin} and Dagmar {Zaoralová} and Michal {Otyepka} and Martin {Pumera}", title="Multiresponsive 2D Ti3C2Tx MXene via Implanting Molecular Properties", journal="ACS Nano (e-ISSN)", year="2021", volume="15", number="6", pages="10067--10075", doi="10.1021/acsnano.1c01742", issn="1936-086X", url="https://pubs.acs.org/doi/10.1021/acsnano.1c01742" }