Detail publikace

Electrically reading a light-driven molecular switch on 2D-Ti3C2Tx MXene via molecular engineering: towards responsive MXetronics

MUÑOZ MARTIN, J. PALACIOS CORELLA, M. PUMERA, M.

Originální název

Electrically reading a light-driven molecular switch on 2D-Ti3C2Tx MXene via molecular engineering: towards responsive MXetronics

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

The contemporary digital revolution, which demands for miniaturized electronics, has prompted the search for molecule-based nanomaterials that handle some of the computational logic functions-which relates the concept of zeros (0) and ones (1) in binary code-reached by mainstream silicon-based semiconductor technology. Herein, the feasibility of emerging 2D transition metal carbide (MXene) derivatives to write, erase and readout bistable molecular switches has been elucidated. As a first demonstration of applicability, 2D-Ti3C2Tx MXene has been covalently functionalized with an optically active molecule as azobenzene (AZO), in which the photo-driven inputs of the AZO isomerization (E-AZO@Ti3C2Tx <-> Z-AZO@Ti3C2Tx) resulted in two distinguished electrical states when it was immobilized in an emerging 3D-printed transducer. Thus, this work provides the basis towards the yet undisclosed concept of "Responsive MXetronics" by molecularly engineering smart MXenes to perform logic (opto)electronic tasks.

Klíčová slova

AZOBENZENE; GRAPHENE; TI3C2TX

Autoři

MUÑOZ MARTIN, J.; PALACIOS CORELLA, M.; PUMERA, M.

Vydáno

17. 8. 2022

Nakladatel

Royal Society of Chemistry

Místo

CAMBRIDGE

ISSN

2050-7496

Periodikum

Journal of Materials Chemistry A

Ročník

10

Číslo

32

Stát

Spojené království Velké Británie a Severního Irska

Strany od

17001

Strany do

17008

Strany počet

8

URL

https://pubs.rsc.org/en/content/articlelanding/2022/TA/D2TA03349F

Plný text v Digitální knihovně

http://hdl.handle.net/11012/208481

BibTex

@article{BUT179181,
  author="Jose Maria {Muñoz Martin} and Mario {Palacios Corella} and Martin {Pumera}",
  title="Electrically reading a light-driven molecular switch on 2D-Ti3C2Tx MXene via molecular engineering: towards responsive MXetronics",
  journal="Journal of Materials Chemistry A",
  year="2022",
  volume="10",
  number="32",
  pages="17001--17008",
  doi="10.1039/d2ta03349f",
  issn="2050-7496",
  url="https://pubs.rsc.org/en/content/articlelanding/2022/TA/D2TA03349F"
}