Detail publikace

Physico-Chemical Properties of Lithium Silicates Related to Their Utilization for Concrete Densifiers

KALINA, L. BÍLEK, V. SEDLAČÍK, M. CÁBA, V. SMILEK, J. ŠVEC, J. BARTONÍČKOVÁ, E. ROVNANÍK, P. FLÁDR, J.

Originální název

Physico-Chemical Properties of Lithium Silicates Related to Their Utilization for Concrete Densifiers

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

Protection of concrete against aggressive influences from the surrounding environment becomes an important step to increase its durability. Today, alkali silicate solutions are advantageously used as pore-blocking treatments that increase the hardness and impermeability of the concrete’s surface layer. Among these chemical substances, known as concrete densifiers, lithium silicate solutions are growing in popularity. In the present study, the chemical composition of the lithium silicate densifiers is put into context with the properties of the newly created insoluble inorganic gel responsible for the micro-filling effect. Fourier-transform infrared spectroscopy was used as a key method to describe the structure of the formed gel. In this context, the gelation process was studied through the evolution of viscoelastic properties over time using oscillatory measurements. It was found that the gelation process is fundamentally controlled by the molar ratio of SiO2 and Li2O in the densifier. The low SiO2 to Li2O ratio promotes the gelling process, resulting in a rapidly formed gel structure that affects macro characteristics, such as water permeability, directly related to the durability of treated concretes.

Klíčová slova

concrete densifier; lithium silicate; surface treatment; gelation process

Autoři

KALINA, L.; BÍLEK, V.; SEDLAČÍK, M.; CÁBA, V.; SMILEK, J.; ŠVEC, J.; BARTONÍČKOVÁ, E.; ROVNANÍK, P.; FLÁDR, J.

Vydáno

8. 3. 2023

Nakladatel

MDPI

Místo

Basel

ISSN

1996-1944

Periodikum

Materials

Ročník

16

Číslo

6

Stát

Švýcarská konfederace

Strany počet

10

URL

https://www.mdpi.com/1996-1944/16/6/2173

Plný text v Digitální knihovně

http://hdl.handle.net/11012/209220

BibTex

@article{BUT183154,
  author="Lukáš {Kalina} and Vlastimil {Bílek} and Martin {Sedlačík} and Vladislav {Cába} and Jiří {Smilek} and Jiří {Švec} and Eva {Bartoníčková} and Pavel {Rovnaník} and Josef {Fládr}",
  title="Physico-Chemical Properties of Lithium Silicates Related to Their Utilization for Concrete Densifiers",
  journal="Materials",
  year="2023",
  volume="16",
  number="6",
  pages="10",
  doi="10.3390/ma16062173",
  issn="1996-1944",
  url="https://www.mdpi.com/1996-1944/16/6/2173"
}