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SMÍSITEL, P. ŠIMŮNKOVÁ, H. CHMELA, O. CLAROS VARGAS, M. VALLEJOS VARGAS, S. HUBÁLEK, J.
Originální název
Electrical characterization of hydrothermally synthesized manganese dioxide nanowires with regard to NO2 adsorption/desorption thermodynamics
Typ
článek ve sborníku ve WoS nebo Scopus
Jazyk
angličtina
Originální abstrakt
Single nanowires (NWs) are promising structures to improve sensitivity and selectivity of metal-oxide (MOX) gas sensors. Self-made MnO2 nanowires were hydrothermally synthesized and electrically characterized in different ambient. The nanowires were approximately 4-10 µm long and about 100 nm in diameter. The nanowires were suspended in water and deposited on two parallel gold electrodes having separation distance of 4 µm. Single nanowires were aligned perpendicularly across the gold electrodes by dielectrophoresis (DEP) technique. The number of the NWs was determined by scanning electron microscopy. The conductivity was measured in synthetic air, nitrogen, and in NO2 ambient. The tests consisted in measuring resistivity of the NWs in relation to temperature of the bottom-placed heater under the chip. The temperature went from room temperature up to 300°C. The resistivity changes were observed accounting for oxygen reduction on the NWs surface as the electrons were moving from the NWs to the oxygen. The resistivity was explored at a constant current arrangement test. Based on resistivity changes, electrical properties, such as activation energy and a type of semiconductor (p-type in case of MnO2), were evaluated. Mott-Schottky analysis was applied to estimate acceptor concentration, as well as NWs permittivity.
Klíčová slova
MnO2 nanowires, dielectrophoresis, gas sensing, resistivity, Mott-Schottky analysis
Autoři
SMÍSITEL, P.; ŠIMŮNKOVÁ, H.; CHMELA, O.; CLAROS VARGAS, M.; VALLEJOS VARGAS, S.; HUBÁLEK, J.
Vydáno
18. 9. 2023
Nakladatel
MDPI
ISSN
2673-4591
Periodikum
Engineering Proceedings
Ročník
48
Číslo
1
Stát
Švýcarská konfederace
Strany od
Strany do
6
Strany počet
URL
https://www.mdpi.com/2673-4591/48/1/35
Plný text v Digitální knihovně
http://hdl.handle.net/11012/244168
BibTex
@inproceedings{BUT185059, author="Petr {Smísitel} and Helena {Šimůnková} and Ondřej {Chmela} and Martha Carmiňa {Claros Vargas} and Stella {Vallejos Vargas} and Jaromír {Hubálek}", title="Electrical characterization of hydrothermally synthesized manganese dioxide nanowires with regard to NO2 adsorption/desorption thermodynamics", booktitle="Engineering Proceedings", year="2023", journal="Engineering Proceedings", volume="48", number="1", pages="1--6", publisher="MDPI", doi="10.3390/CSAC2023-14883", issn="2673-4591", url="https://www.mdpi.com/2673-4591/48/1/35" }