Detail publikace

Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry

Yu, Zhang Ahmad, Muhammad Sajjad Shen, Boxiong Li, Yingna Ibrahim, Muhammad Bokhari, Awais Klemes, Jiri Jaromir

Originální název

Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

The bioenergy potential of waste textile cotton cellulose (BOC) and the activated waste textile cotton cellulose by H3PO4 (BOP) were assessed in this study. BOC and BOP were pyrolyzed in TG at four heating rates. The thermal weight-loss process of BOC and BOP can be separated into drying stage, rapid pyrolysis stage and carbonization stage. The kinetic and thermodynamic parameters of the pyrolysis reaction were evaluated using an iso-conversion model. The Ea, Delta H and Delta G values of BOC are 84.79-206.79 kJ mol(-1), 159.85-318.88 kJ mol(-1) and 357.72-359.16 kJ mol-1, respectively. The Ea, & UDelta;H and & UDelta;G values of BOP are 101.81-453.85 kJ mol -1, 169.11-389.47 kJ mol-1 and 257 similar to 335.78 kJ mol-1, respectively. Py-GC/MS analysis illustrated that the peak area percentages of the products of BOC/BOP, including Glucopyranose, Ketones, Cycloalkane, Aromatic, Furan, Aliphatic, CO2, and others, were 47.7%/5%, 4.66%/30.41%, 0%/27.12%, 16.64%/3.22%, 8.55%/12.44%, 12.75%/13.29%, 4.19%/3.91% and 5.51%/4.61%, respectively. Compared with BOC, the low-quality products of BOP, Glucopyranose and Aromatic, decreased from 47.7% to 16.64%-5% and 3.22%, respectively, and the high-quality products, Ketone and Cycloalkane, increased from 4.66% to 0%-30.41% and 27.12%, respectively. The complexity of bio-oil of BOP is reduced, which gives a positive prospect for the purification of backward position.

Klíčová slova

Kinetic parameters; Py-GC/MS; Pyrolysis; Thermodynamic analysis; Waste textile cotton cellulose

Autoři

Yu, Zhang; Ahmad, Muhammad Sajjad; Shen, Boxiong; Li, Yingna; Ibrahim, Muhammad; Bokhari, Awais; Klemes, Jiri Jaromir

Vydáno

15. 11. 2023

Nakladatel

PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

Místo

PERGAMON-ELSEVIER SCIENCE LTDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND

ISSN

0360-5442

Periodikum

Energy

Číslo

283

Stát

Spojené království Velké Británie a Severního Irska

Strany počet

12

URL

https://www.sciencedirect.com/science/article/pii/S0360544223017358?via%3Dihub

BibTex

@article{BUT187483,
  author="Yu, Zhang and Ahmad, Muhammad Sajjad and Shen, Boxiong and Li, Yingna and Ibrahim, Muhammad and Bokhari, Awais and Klemes, Jiri Jaromir",
  title="Activated waste cotton cellulose as renewable fuel and value-added chemicals: Thermokinetic analysis, coupled pyrolysis with gas chromatography and mass spectrometry",
  journal="Energy",
  year="2023",
  number="283",
  pages="12",
  doi="10.1016/j.energy.2023.128341",
  issn="0360-5442",
  url="https://www.sciencedirect.com/science/article/pii/S0360544223017358?via%3Dihub"
}