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ABDELLATIF, A. ABDEL-RAHMAN, R. KALINA, L. VISHAKHA, V. KAPRÁLKOVÁ, L. NĚMEČEK, P. JANČÁŘ, J. KELNAR, I.
Originální název
Effect of Chitin Nanocrystal Deacetylation on a Nature-Mimicking Interface in Carbon Fiber Composites
Typ
článek v časopise ve Web of Science, Jimp
Jazyk
angličtina
Originální abstrakt
The formation of a rigid, tough interface based on a nacre-like structure in carbon fiber (CF) composites is a promising way to eliminate low delamination resistance. An effective method of coating CFs is electrophoretic deposition (EPD), which, in the case of dissimilar components like graphene oxide (GO) and polymeric glue, usually requires chemical bonding/strong interactions. In this work, we focus on chitin nanocrystals (ChNCs), leading to an excellent mechanical performance of artificial nacre, where favorable interactions and bonding with GO are controlled by degrees of deacetylation (5, 15, and 30%). We prepared coatings based on GO/ChNC adducts with 95/5, 90/10, 50/50, and 25/75 ratios using optimized EPD conditions (pH, concentration, voltage, and time). The prepared materials were characterized using FTIR, TEM, XPS, SEM, DLS, and XRD. SEM evaluation indicates the formation of a homogeneous interlayer, which has a fair potential for chemical bonding with the epoxy matrix. Short-beam testing of epoxy matrix composites indicates that the coating does not decrease stiffness and has a relatively low dependence on composition. Therefore, all coatings are promising for a detailed study of delamination resistance using laminate samples. Moreover, facile EPD from the water solution/suspension has a fair potential for industrial applications.
Klíčová slova
graphene oxide; chitin nanocrystals; delamination resistance; tough interface; electrophoresis; carbon fiber composite
Autoři
ABDELLATIF, A.; ABDEL-RAHMAN, R.; KALINA, L.; VISHAKHA, V.; KAPRÁLKOVÁ, L.; NĚMEČEK, P.; JANČÁŘ, J.; KELNAR, I.
Vydáno
1. 5. 2024
Nakladatel
MDPI
Místo
BASEL
ISSN
2504-477X
Periodikum
Journal of Composites Science
Ročník
8
Číslo
5
Stát
Švýcarská konfederace
Strany počet
16
URL
https://www.mdpi.com/2504-477X/8/5/163
Plný text v Digitální knihovně
http://hdl.handle.net/11012/249466
BibTex
@article{BUT188817, author="Abdelmohsen Moustafa {Abdellatif} and Rasha {Radwan} and Lukáš {Kalina} and Vishakha {Vishakha} and Ludmila {Kaprálková} and Pavel {Němeček} and Josef {Jančář} and Ivan {Kelnar}", title="Effect of Chitin Nanocrystal Deacetylation on a Nature-Mimicking Interface in Carbon Fiber Composites", journal="Journal of Composites Science", year="2024", volume="8", number="5", pages="16", doi="10.3390/jcs8050163", issn="2504-477X", url="https://www.mdpi.com/2504-477X/8/5/163" }