Detail publikace

Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode

VANÝSEK, P. TAVASSOL, H. PILSON, K.

Originální název

Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode

Typ

článek ve sborníku ve WoS nebo Scopus

Jazyk

angličtina

Originální abstrakt

The tacit assumption in an electrochemical experiment is that a properly set up electrochemical cell, working electrode, counter electrode, reference electrode and a potentiostat, will perform an experiment by "applying potential on the working electrode" without any need to consider the properties of the reference electrodes, the effect of electrochemistry on the counter electrode and the real properties of the potentiostat. While this is in first approximation a valid assumption, in the extremes it is also necessary to consider the other parts of the system. In this work we visit two interesting cases that may lead to experimental artifacts. The first is the effect of electrochemical solution changes during impedance measurement. The second is effect of the time constant of a reference electrode on an impedance measurement in an electrochemical cell.

Klíčová slova

impedance; 3-electrode cell; potentiostat; experimental artifact;

Autoři

VANÝSEK, P.; TAVASSOL, H.; PILSON, K.

Rok RIV

2014

Vydáno

5. 12. 2014

Nakladatel

The Electrochemical Society

Místo

Pennington, NJ

ISBN

978-1-62332-230-4

Kniha

15th International Conference on Advanced Batteries, Accumulators and Fuel Cells (ABAF 2014)

ISSN

1938-6737

Periodikum

ECS Transaction

Ročník

63

Číslo

1

Stát

Spojené státy americké

Strany od

145

Strany do

155

Strany počet

11

URL

http://ecst.ecsdl.org/content/63/1/145.abstract

BibTex

@inproceedings{BUT112070,
  author="Petr {Vanýsek} and Hadi {Tavassol} and Kate-Leigh {Pilson}",
  title="Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode",
  booktitle="15th International Conference on Advanced Batteries, Accumulators and Fuel Cells (ABAF 2014)",
  year="2014",
  journal="ECS Transaction",
  volume="63",
  number="1",
  pages="145--155",
  publisher="The Electrochemical Society",
  address="Pennington, NJ",
  doi="10.1149/06301.0145ecst",
  isbn="978-1-62332-230-4",
  issn="1938-6737",
  url="http://ecst.ecsdl.org/content/63/1/145.abstract"
}