Detail publikace

Rapid Distinguishing between Rhodium and Palladium in Highly Contaminated Waters Using Amperometry

HEGER, Z. KOMÍNKOVÁ, M. ZÍTKA, O. BEKLOVÁ, M. ADAM, V. KIZEK, R.

Originální název

Rapid Distinguishing between Rhodium and Palladium in Highly Contaminated Waters Using Amperometry

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

A rapid, electrochemical method for determination of RhCl3 and PdCl2 was developed. With respect to behavior of studied PGEs in the environment, we chose acetate and borate buffer with different pH to investigate their electrochemical behavior using planar glassy carbon electrode. Rh was determined without difficulties in the first step, which was based on the application of borate buffer (pH 7) and detection potential of 1000 mV. In the second step mobile phase is changed from borate to acetate buffer (pH 4) and detection potential is increased to 1100 mV. Based on these, we are able to distinguish the metals.

Klíčová slova

Flow Injection Analysis with Electrochemical Detection; Hydrodynamic Voltammograms; Rapid Distinguishing; Palladium; Rhodium

Autoři

HEGER, Z.; KOMÍNKOVÁ, M.; ZÍTKA, O.; BEKLOVÁ, M.; ADAM, V.; KIZEK, R.

Vydáno

1. 6. 2016

ISSN

1452-3981

Periodikum

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE

Ročník

11

Číslo

6

Stát

Srbská republika

Strany od

4645

Strany do

4657

Strany počet

13

BibTex

@article{BUT126822,
  author="Zbyněk {Heger} and Markéta {Komínková} and Ondřej {Zítka} and Miroslava {Beklová} and Vojtěch {Adam} and René {Kizek}",
  title="Rapid Distinguishing between Rhodium and Palladium in Highly Contaminated Waters Using Amperometry",
  journal="INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE",
  year="2016",
  volume="11",
  number="6",
  pages="4645--4657",
  doi="10.20964/2016.06.29",
  issn="1452-3981"
}