Detail publikace

Glycolated Thiophene-Tetrafluorophenylene Copolymers for Bioelectronic Applications: Synthesis by Direct Heteroarylation Polymerisation

Zachary S. Parr, Roman Halaksa, Peter A. Finn, Reem B. Rashid,Jonathan Rivnay, Jozef Krajčovič, Christian B. Nielsen

Originální název

Glycolated Thiophene-Tetrafluorophenylene Copolymers for Bioelectronic Applications: Synthesis by Direct Heteroarylation Polymerisation

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

A series of copolymers contg. a glycolated 1,​4-​dithienyl-​2,​3,​5,​6-​tetrafluorophenylene unit copolymd. with thiophene, bithiophene, thienothiophene and 1,​2,​4,​5-​tetrafluorobenzene comonomer units were designed and synthesized by direct heteroarylation polymn. The optical, electrochem., electrochromic and solid-​state structural properties of the copolymers were investigated. The copolymers exhibit stable redox properties in org. solvents and promising redox properties in thin film configuration with an aq. electrolyte. Finally, the potential of the copolymers as active materials in org. electrochem. transistors (OECTs) was assessed, and promising performance was shown as an accumulation-​mode OECT material with a peak transconductance of 0.17 mS and a good on​/off ratio of 105 for the thiophene copolymer.

Klíčová slova

bioelectronic applications, glycolated copolymers, organic electrochemical transistors

Autoři

Zachary S. Parr, Roman Halaksa, Peter A. Finn, Reem B. Rashid,Jonathan Rivnay, Jozef Krajčovič, Christian B. Nielsen

Vydáno

17. 6. 2019

Nakladatel

WILEY-V C H VERLAG GMBH

Místo

Německo

ISSN

2192-6506

Periodikum

ChemPlusChem

Ročník

84

Číslo

9

Stát

Spolková republika Německo

Strany od

1384

Strany do

1390

Strany počet

7

URL

https://onlinelibrary.wiley.com/doi/pdf/10.1002/cplu.201900254

BibTex

@article{BUT157970,
  author="Jozef {Krajčovič} and Alexander {Kovalenko} and Martin {Weiter} and Roman {Halaksa}",
  title="Glycolated Thiophene-Tetrafluorophenylene Copolymers for Bioelectronic Applications: Synthesis by Direct
Heteroarylation Polymerisation",
  journal="ChemPlusChem",
  year="2019",
  volume="84",
  number="9",
  pages="1384--1390",
  doi="10.1002/cplu.201900254",
  issn="2192-6506",
  url="https://onlinelibrary.wiley.com/doi/pdf/10.1002/cplu.201900254"
}