Detail publikace

Coordination chemistry of 2D and layered gray arsenic: photochemical functionalization with chromium hexacarbonyl

ŠTURALA, J. SOFER, Z. PUMERA, M.

Originální název

Coordination chemistry of 2D and layered gray arsenic: photochemical functionalization with chromium hexacarbonyl

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

The functionalization of layered materials is one of the current challenges in material science. Exfoliated rhombohedral (gray) arsenic represents a promising layered material for the fabrication of electronic devices and sensors; however, synthetic protocols for tuning its properties or protecting the surface by covalent functionalization are not known. In this communication, we present its covalent functionalization accompanied by the exfoliation of rhombohedral arsenic in the presence of ultraviolet light irradiation and chromium hexacarbonyl. During this modification, the arsenic atoms act as ligands to the chromium metal center. We believe that this study provides a promising approach for the modification of rhombohedral few-layer arsenene and enables its application in various fields, including electronic devices, sensors, and energy devices.

Klíčová slova

BLACK PHOSPHORUS; NONCOVALENT FUNCTIONALIZATION; METAL-CARBONYLS

Autoři

ŠTURALA, J.; SOFER, Z.; PUMERA, M.

Vydáno

1. 12. 2019

ISSN

1884-4057

Periodikum

NPG Asia Materials

Ročník

11

Číslo

1

Stát

Japonsko

Strany od

1

Strany do

7

Strany počet

7

URL

https://www.nature.com/articles/s41427-019-0142-x

BibTex

@article{BUT158512,
  author="Jiří {Šturala} and Zdeněk {Sofer} and Martin {Pumera}",
  title="Coordination chemistry of 2D and layered gray arsenic: photochemical functionalization with chromium
hexacarbonyl",
  journal="NPG Asia Materials",
  year="2019",
  volume="11",
  number="1",
  pages="1--7",
  doi="10.1038/s41427-019-0142-x",
  issn="1884-4057",
  url="https://www.nature.com/articles/s41427-019-0142-x"
}