Detail publikace

Novel Cu(II)-based metal-organic framework STAM-1 as a sulfur host for Li-S batteries

NIŠČÁKOVÁ, V. ALMÁŠI, M. CAPKOVÁ, D. KAZDA, T. ČECH, O. ČUDEK, P. PETRUŠ, O. VOLAVKA, D. ORINAKOVÁ, R. STRAKOVÁ FEDORKOVÁ, A.

Originální název

Novel Cu(II)-based metal-organic framework STAM-1 as a sulfur host for Li-S batteries

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

Due to the increasing demand for energy storage devices, the development of high-energy density batteries is very necessary. Lithium-sulfur (Li-S) batteries have gained wide interest due to their particularly high-energy density. However, even this type of battery still needs to be improved. Novel Cu(II)-based metal-organic framework STAM-1 was synthesized and applied as a composite cathode material as a sulfur host in the lithium-sulfur battery with the aim of regulating the redox kinetics of sulfur cathodes. Prepared STAM-1 was characterized by infrared spectroscopy at ambient temperature and after in-situ heating, elemental analysis, X-ray photoelectron spectroscopy and textural properties by nitrogen and carbon dioxide adsorption at - 196 and 0 degrees C, respectively. Results of the SEM showed that crystals of STAM-1 created a flake-like structure, the surface was uniform and porous enough for electrolyte and sulfur infiltration. Subsequently, STAM-1 was used as a sulfur carrier in the cathode construction of a Li-S battery. The charge/discharge measurements of the novel S/STAM-1/Super P/PVDF cathode demonstrated the initial discharge capacity of 452 mAh g-1 at 0.5 C and after 100 cycles of 430 mAh g-1, with Coulombic efficiency of 97% during the whole cycling procedure at 0.5 C. It was confirmed that novel Cu-based STAM-1 flakes could accelerate the conversion of sulfur species in the cathode material.

Klíčová slova

Lithium-sulfur battery; Cathode materials; Metal-organic framework; Energy storage

Autoři

NIŠČÁKOVÁ, V.; ALMÁŠI, M.; CAPKOVÁ, D.; KAZDA, T.; ČECH, O.; ČUDEK, P.; PETRUŠ, O.; VOLAVKA, D.; ORINAKOVÁ, R.; STRAKOVÁ FEDORKOVÁ, A.

Vydáno

22. 4. 2024

Nakladatel

NATURE PORTFOLIO

Místo

BERLIN

ISSN

2045-2322

Periodikum

Scientific Reports

Ročník

14

Číslo

1

Stát

Spojené království Velké Británie a Severního Irska

Strany od

1

Strany do

16

Strany počet

16

URL

https://www.nature.com/articles/s41598-024-59600-8

Plný text v Digitální knihovně

http://hdl.handle.net/11012/249908

BibTex

@article{BUT189067,
  author="V. {Niščáková} and Miroslav {Almáši} and Dominika {Capková} and Tomáš {Kazda} and Ondřej {Čech} and Pavel {Čudek} and Ondrej {Petruš} and D. {Volavka} and Renáta {Orinaková} and Andrea {Straková Fedorková}",
  title="Novel Cu(II)-based metal-organic framework STAM-1 as a sulfur host for Li-S batteries",
  journal="Scientific Reports",
  year="2024",
  volume="14",
  number="1",
  pages="1--16",
  doi="10.1038/s41598-024-59600-8",
  issn="2045-2322",
  url="https://www.nature.com/articles/s41598-024-59600-8"
}