Publication detail

Synthesis and characterization of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group

VYŠVAŘIL, M. DASTYCH, D. TARABA, J. NEČAS, M.

Original Title

Synthesis and characterization of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group

Type

journal article in Web of Science

Language

English

Original Abstract

A series of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group were synthesized and characterized by 1H, 13C{1H} and 31P NMR spectroscopy, IR and MS. PhmPCln (m = 3; n, n = 3, 2, 1) reacted with 3,3,4,4-tetramethylsuccinimide (TH) and potassium 3,3,4,4-tetramethylsuccinimidate to give corresponding PhmPTn. Molecular structures of products were established by single-crystal X-ray diffraction experiments. Attempts to prepare new imidophosphoranes by reactions of 1 with PhmPCln (m = 5; n, n = 4, 3, 2) resulted in phosphine oxides. In these reactions the phosphoryl group was formed and we characterized a by-product of this type of reaction.

Keywords

succinimide, phosphanes, phosphine oxides, substitution, phosphoryl group

Authors

VYŠVAŘIL, M.; DASTYCH, D.; TARABA, J.; NEČAS, M.

Released

10. 11. 2009

Publisher

Elsevier

ISBN

0020-1693

Periodical

INORGANICA CHIMICA ACTA

Year of study

2009

Number

362

State

Swiss Confederation

Pages from

4899

Pages to

4905

Pages count

7

BibTex

@article{BUT48955,
  author="VYŠVAŘIL, M. and DASTYCH, D. and TARABA, J. and NEČAS, M.",
  title="Synthesis and characterization of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group",
  journal="INORGANICA CHIMICA ACTA",
  year="2009",
  volume="2009",
  number="362",
  pages="4899--4905",
  issn="0020-1693"
}